In order to reveal the reactivity of toluenethiols, the hydrogen isotope exchange reaction between one of three toluenethiols (o–,m–, andp–) and poly (vinyl alcohol) labeled with tritium was observed at 50 90°C. The reaction was analyzed with both the data obtained and theA
-McKay plot method, and the following has been quantitatively clarified: (1) the reactivity order of toluenethiols is (o–>(m–)>(p–); (2) the temperature dependences of the reactivity of toluenethiols are nearly equal; (3) the reactivity of benzenethiol is considerably decreased by the CH3 group bonded to the ortho position.
Making a costly apology or inflicting self-punishment after an unintentional transgression can serve as a costly signal of the transgressor's benign intention. In the present research, after an unintentional transgression (i.e., unequal resource allocation between themselves and a partner), participants were provided with an opportunity to send an apology message to their partner (in Experiments 1 and 2) or to privately deduct some amount from their own reward (in Experiments 2 and 3). Across these experiments, approximately half of the participants indicated their willingness to incur some cost to produce these costly signals. In Experiment 1, neither history nor expectation of interaction with a partner altered the frequency of a costly apology. In Experiment 2, despite explicit instructions that their partner would not be informed whether they had inflicted the self-punishment, the frequency of self-punishment was approximately equal to that of a costly apology. These results suggest that the two types of costly signal were not solely directed at the victim. Experiment 3 revealed that these costly signallers endorsed the equality principle more than the non-signallers. This result is consistent with the idea that the two forms of costly signals serve to protect the signaller's reputation as a fair person.
A new spectrophotometric determination of technetium has been developed by means of the solvent extraction of tris(1,10-phenanthroline)iron(II) ([Fe(phen)32+]) with pertechnetate into nitrobenzene. The concentration of technetium can be determined by measuring the characteristic absorbance at 516 nm (=11,700M–1·cm–1) in the organic phase. An important feature of the proposed method is that the concentration of pertechnetate can be determined without complicated processes such as the reduction of pertechnetate and the subsequent formation of a colored chelate.