Authors:K. Mészáros-Szécsényi, E. Ivegeš, V. Leovac, A. Kovács, G. Pokol, and Ž. Jaćimović
Complexes represented by the general formula [MCl2L2] (M(II)=Zn, Mn, Co) and complexes of [Cu3Cl6L4] and CuSO4L24H2O, CoSO4L23H2O, [ZnSO4L3] where L stands for 3-amino-5-methylpyrazole were prepared. The complexes were characterized by elemental analysis, FT-IR
spectroscopy, thermal (TG, DTG, DSC and EGA) methods and molar conductivity measurements. Except for the Zn-complexes, the
magnetic susceptibilities were also determined.
Thermal decomposition of the sulphato complexes of copper(II) and cobalt(II) and the chloro complexes of cobalt(II) and manganese(II)
resulted in well-defined intermediates. On the basis of the IR spectra and elemental analysis data of the intermediates a
decomposition scheme is proposed.
Authors:A. F. Petrović, S. R. Lukić, D. M. Petrović, E. Z. Ivegeš, and V. M. Leovac
The thermal decomposition of tetrahedral cobalt(II) complexes with 3(5)-amino-4-acetyl5(3)-methylpyrazole (HL) of the general formula [Co(HL)2X2] (X=Cl, Br, I, NCO, NCS) and octahedral [Co(HL)2(H2O)4](NO3)2 and [Co(HL)2−N(CN)2}2] complexes was investigated in air atmosphere in the interval from room temperature to 1000°C. Decomposition of the complexes occurred in several successive endothermic and exothermic processes, and the residue was in all cases CoO.