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Journal of Thermal Analysis and Calorimetry
Authors:
F. J. Martínez Casado
,
M. Ramos Riesco
,
M. I. Redondo Yélamos
,
A. Sánchez Arenas
, and
J. A. Rodríguez Cheda

Abstract

Four mesomorphic states of matter are known: liquid crystal, plastic crystal, condis phase, and rotator phase, all of them are solid phases, except liquid crystal, which is fluid. Plastic crystal (also called ODIC, orientational disordered crystal), rotator phase, and even condis phase have been considered the same phase by many authors. Differences between them will be established to define their own characteristics. Two organic salts series have been used for discussion in this presentation: (1) thallium(I) alkanoate series, that presents a condis mesophase, and (2) lead(II) alkanoate series, that present a rotator one, both forming a smectic A-like liquid crystal phase. Based in the literature data of the alkyl ammonium bromide series it can be established that the short chain length members would present a rotator phase, and, the large chain ones, a condis phase. Five different glass states are known (four with partial crystalline order), corresponding with the above mentioned mesophases, and the ordinary (amorphous) glass state.

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Abstract

Mechanical properties of ductile materials are very sensitive to environmental conditions in particular temperature. The paper shows the results obtained in the simultaneous testing of 5182 H111 Aluminium alloy, S275JR Carbon Steel and F114 Carbon Steel specimens using conventional methods and thermography. The infrared thermography was used to quantify deformation localization zones, also to relate the temperature changes of the specimens, continuously recorded by thermography, with the load extension diagram. It enables to predict reaching the critical stresses which cause the appearance of fractures and to define the criteria for determining the maximum sample temperature alteration in the field of elastic and elastic-plastic strains. Infrared thermography was found to be an efficient tool for investigating the deformation and damage scenario under tensile loading.

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