The characteristics of crystallization, melting and spherulitic growth of a random propylene copolymer (PRC) containing small amount of ethylene were studied in the presence of a selective Β-nucleating agent (calcium pimelate). It was established that the products of isothermal and non-isothermal crystallization are very rich in Β-modification but have mixed polymorphic composition. The formation of α-modification may be attributed to Βα-transition on the surface of growing Β-spherulites resulting in αΒ-twin-spherulites. During melting of PRC of Β-modification, the characteristics observed with Β-nucleated propylene homopolymers, namely, a Βα-recrystallization of recooled samples and separated melting of non-recooled samples (i.e. the melting memory effect), as well as a ΒΒ-recrystallization leading to a perfection of the structure within the Β-modification, are also demonstrated. The disturbance of regularity of the polymer chain highly reduces the tendency to Β-crystallization. In contrast to the observations with propylene homopolymers, the growth rate of α-modification (Gα) is higher than that of Β-modification (Gβ) and no critical crossover temperature can be found (T(Βα)=413 K) below whichGα>Gβ. The experimental results show that a partial disturbance of chain regularity by incorporation of comonomer units considerably reduces the tendency to Β-crystallization.
Authors:K. Gribovszki, F. Schulek-Tóth, and P. Varga
Deterministic seismic hazard computations were performed along four different profiles across the downtown of Budapest. Synthetic seismograms were computed by the so called “hybrid technique”. By applying the hybrid technique it is possible to take into account the focal source, the path and the site effect together. Four independent computations have been performed using the same seismic source but different profiles. The parameters of the seismic source were adopted from the parameters of the well-known 1956 Dunaharaszti earthquake. The focal mechanism and the homogeneous and heterogeneous parts of the profiles are known from geophysical and geological data of the investigated area.As the results of the computations PGA (peak ground acceleration) grid maps of the downtown of Budapest for the three different components came into existence. Furthermore spectral acceleration (response spectra, SA) and RSR charts of the synthetic seismograms for the four different profiles were created. The PGA grid maps show that the maximal PGA values are situated at the eastern (Pest) part of the downtown, and their values are 50–200 cm/s
.For the downtown of Budapest a special seismic risk map have been prepared. This special seismic risk map were created on the basis of the difference between the maximal amplitude frequencies of SA of synthetic seismograms and the building’s eigenfrequencies at every 0.1 km
of the downtown. In order to determine the building’s eigenfrequencies microseismic noise measurement were performed at 6 different buildings in the downtown. The special seismic risk map shows that the buildings situated at the hilly western section of the downtown have higher seismic risk than the ones at the flat eastern part.