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A new method is proposed for the determination of kinetic parameters, where Reich's method is a special case. This method involves a knowledge of the values of the weight loss, the temperature, the rate of weight loss and the derivative of the rate of weight loss, corresponding to a certain point in the TG curve. The findings are in good agreement with those of Reich's method.

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The paper discusses three fast methods for determination of the reaction order, as follows: the single-point method proposed by Kissinger, Horowitz and Metzger, an original two-point method, and the three-point method suggested by a Gorbachev's paper. These methods cannot elucidate the reaction mechanism, but they can help in the rapid derivation of the apparent kinetic parametersn andE.

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Determination of the kinetic parameters of polyvinylchloride

I. Dehydrochlorination at low conversions

Journal of Thermal Analysis and Calorimetry
I. Agherghinei
A. Airinei
E. Buruiană
, and
A. Caraculacu
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