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Journal of Thermal Analysis and Calorimetry
Authors:
N. Sbirrazzuoli
,
L. Vincent
,
J. Bouillard
, and
L. Elégant
Abstract
In the case of a complex mechanism of two parallel independent reactions, peak maximum evolution methods and model-fitting methods give only a mean value of the kinetic parameters, while isoconversional methods are useful to describe the complexity of the mechanism. Isothermal and non-isothermal isoconversional methods can be used to elucidate the kinetics of the process. Nevertheless, isothermal isoconversional methods can be limited by restrictions on the temperature regions experimentally available because of duration times or detection limits.
