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Some indigodisulphonates of Cr(III), Cu(II), Ag(I), An(II) and Cd(II) have been prepared in aqueous medium and characterized on the basis of elemental analyses, diffuse reflectance infrared spectra and magnetic measurements.

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Thermal studies on metal complexes of 5-nitroso-pyrimidine derivatives

III. Thermal behaviour of Hg(II) complexes of 6-amino-5-nitrosouracil derivatives

Journal of Thermal Analysis and Calorimetry
Authors: M. Moreno-Carretero and J. Salas-Peregrín

Four Hg(II) complexes, containing as ligands 6-amino-5-nitrosouracil (AH), 6-amino-3-methyl-5-nitrosouracil (BH) or 6-amino-1-methyl-5-nitrosouracil (CH), have been synthesized and their thermal behaviour studied by TG and DSC techniques: Hg3Cl6(AH)4, HgCl2(BH)2· 2 H2O, HgCl2(BH)2 · H2O and HgC2· 2 H2O.

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Thermal studies on metal complexes of 5-nitroso-pyrimidine derivatives

II. Thermal behaviour of Cd(II) complexes of 6-amino-5-nitroso-uracil derivatives

Journal of Thermal Analysis and Calorimetry
Authors: M. Moreno-Carretero and J. Salas-Peregrín

The following cadmium(II) complexes of deprotonated 6-amino-5-nitroso-uracil (AH), deprotonated 6-amino-3-methyl-5-nitroso-uracil (BH) and neutral 6-amino-1-methyl-5--nitroso-uracil (CH) have been prepared and their thermal behaviour studied by TG and DSC techniques: CdA2 · 3 H2O, CdB2 · 2 H2O, CdB2 and CdCl2(CH)2 · 2 H2O.

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Thermal studies on metal complexes of 5-nitrosopyrimidine derivatives

VI. Thermal behaviour of Zn(II), Cd(II), Hg(II) and Hg(I) complexes of 4-amino-1,6-dihydro-2-methylthio-5-nitroso-6-oxopyrimidine

Journal of Thermal Analysis and Calorimetry
Authors: M. P. Sánchez -Sánchez, J. M. Salas -Peregrín, M. A. Romero -Molina, and J. Ruiz Sánchez

The following Zn(II), Cd(II), Hg(II) and Hg(I) complexes of 4-amino-1,6-dihydro-2-methylthio-5-nitroso-6-oxopyrimidine (MTH) have been prepared and their thermal behaviour studied by TG and DSC techniques: Zn(MT)2·3H2O, Cd(MT)·H2O. Cd(MTH)Cl2, Hg(MTH)Cl2 and Hg2(MT)(NO3). The dehydration and dehalogenation enthalpy values were calculated.

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Thermal studies on metal complexes of 5-nitrosopyrimidine derivatives IV

Complexes of Fe(II), Co(II), Ni(II) and Cu(II) with 6-amino-5-nitrosouracil

Journal of Thermal Analysis and Calorimetry
Authors: J. M. Salas-Peregrin, M. A. Romero-Molina, M. A. Ferro-Garcia, and M. N. Moreno-Carretero

The thermal decomposition processes of the complexes of 6-amino-5-nitrosouracil with Fe(II), Co(II), Ni(II) and Cu(II) have been studied using TG and DSC techniques. Dehydration energies have been calculated from the DSC curves.

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4-Ethylphenylamino-N,N-diacetic acid

Synthesis, characterization, thermal behaviour and complexing capacity

Journal of Thermal Analysis and Calorimetry
Authors: J. Salas-Peregrin, J. Suárez-Varela, J. Avila-Rosón, and M. Román-Ceba
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Thermal studies on metal complexes of 5-Nitrosopyrimidine derivatives

V. thermal behaviour of Zn(II), Cd(II), Hg(II) and Hg(I) complexes of 4-amino-5-nitroso-6-oxo-1,2,3,6-tetrahydro-2-thiopyrimidine

Journal of Thermal Analysis and Calorimetry
Authors: M. P. Sánchez-Sánchez, J. M. Salas-Peregrin, and M. A. Romero-Molina

New 4-amino-5-nitroso-6-oxo-1,2,3,6-tetrahyaro-2-thiopyrimidine (TANH) complexes of Zn(II), Cd(II), Hg(II) and Hg(I) were prepared and their thermal behaviour was studied by TG and DSC techniques.

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Journal of Thermal Analysis and Calorimetry
Authors: J. Salas-Peregrin, M. Moreno-Carretero, J. Lopez-Gonzalez, and C. Valenzuela-Calahorro
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Tetrachloroaurates of 8-ethyl-, 8-isopropyl-, 8-propyl- and 8-pentyltheophylline were synthesized and studied by1H-NMR, TG and DSC techniques. The metal is not coordinated to the 8-alkyltheophylline derivatives and forms a salt-like structure.

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Thermal studies on metal complexes of 5-nitroso-pyrimidine derivatives

I. Thermal behaviour of Zn(II) complexes of 6-amino-5-nitrosouracil derivatives

Journal of Thermal Analysis and Calorimetry
Authors: M. N. Moreno-Carretero, J. M. Salas-Peregrín, and A. Mata-Arjona

The following Zn(II) complexes of deprotonated 6-amino-5-nitrosouracil (AH), 6-amino-3-methyl-5-nitrosouracil (BH) and 6-amino-1-methyl-5-nitrosouracil (CH) have been prepared and their thermal behaviour studied by TG and DSC techniques: ZnA2(H2O)2, ZnB2 · 4 H2O, ZnC2 · 4 H2O and ZnC2(H2O)2 · H2O. The values of the dehydration enthalpy of the complexes are in the 31.3–76.5 kJ mol−1 H2O range and, except in the first complex, the dehydration processes take place in several steps. The pyrolysis of the complexes finishes between 540 and 725° C ZnO remaining as residue.

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