The gold content of placer gold flakes and gold bearing ores has been determined by instrumental neutron activation analysis /INAA/ and radiochemical neutron activation analysis /RNAA/. It was discovered that significant errors result in the instrumental method for gold flakes as small as 10 mg due to sample self-absorption of neutrons during irradiation. Reliable results were obtained, for both ore samples and gold flakes, by dissolving the samples in aqua regia prior to irradiation.
Substoichiometric extraction in conjunction with a double tracer technique is employed to simultaneous determination of extraction constants of simple metal pyrrolidinedithiocarbamates and chloride-mixed metal pyrrolidinedithiocarbamates. The metals involved include Hg(II), Bi(III), In(III), As(III), Cd(II) and Fe(II). The extraction constants for Bi(III) and Cd(II) obtained are compared with the values available in the literature. The extraction constants for all the other metals are reported for the first time.
A series of Zn–Al hydrotalcites with Zn/Al molar ratios of 1, 2, 3 and 6 were prepared by co-precipitation method. TG-DTG results showed that the hydrotalcites decompose in two stages, corresponding to the two endothermic peaks around 180 and 220°C. After calcination at 400°C, the samples were converted into Zn–Al mixed oxides with the only XRD pattern of ZnO, except for the sample with the ratio of 6. The Zn–Al mixed oxides possess similar surface acidity revealed by microcalorimetric adsorption of NH3. The basicity of the samples increases with the order: ZnO>6Zn/Al>1Zn/Al>Al2O3.
Carburization and coke deposition of unsupported and carbon-supported Fe, Mo and Fe−Mo catalysts in syngas have been studied
using thermogravimetry. Compositions of the carbides formed are evaluated on the basis of the amount of metals in the catalysts
and amount of carbon deposited during carburization. It is shown that carburization temperature and the nature of the carbides
formed (Fe5C2 and Fe2C for iron and Mo2C for molybdenum) depend on the metals but are influenced by the support and metal loading. Coke deposition on these catalysts
takes place as soon as carburization is complete.
The catalytic performance of unsupported and carbon-supported Fe, Mo and Fe−Mo catalysts for Fischer-Tropsch synthesis is
greatly influenced by the final reduction states of the catalysts. In this investigation, the reduction process of the catalysts
by H2 was studied by using TG-DTG. The reduction process depends not only on the reducibility of metals but also on the nature
of the support. Methanation of the support occurred as soon as the supported metals were completely reduced for the carbon-supported
catalysts. For these, the reduction temperature should by carefully selected so that the metal oxides are reduced as completely
as possible, whilst the methanation of the support must be avoided to obtain optimum reduced catalysts.
Rice straw represents a significant energy source for ruminant animals, and fibers and lignin contents of rice straw are negatively related to intake potential of forages. For improvement of the digestibility of rice straw, it is necessary to understand the genetic basis of the related traits. In present study, mapping of quantitative trait loci (QTL) for acid detergent fiber (ADF), neutral detergent fiber (NDF), and acid detergent lignin (ADL) was carried out using a doubled haploid (DH) population derived from a cross between
variety Zai-Ye-Qing 8 (ZYQ8) and
variety Jing-Xi 17 (JX17). The results indicated that all three parameters were continuously distributed among the DH lines, but many DH lines showed transgressive segregation for all the three traits. A total of three main-effect QTLs were identified for ADF and ADL, two of which, qADF-9 and qADL-9, shared the same region on chromosome 9. These two main-effect QTLs explained more than 20% of the total phenotypic variations, whereas the other QTL, qADF-5, explained 12.8% of the total phenotypic variation for ADF. In addition, another two epistatic QTLs, qADF-2 and qADF-3 could explain 17.6% of the total variations. Thus, we concluded that both main-effects and epistatic QTLs were important in controlling the genetic basis of ADF.
Adsorption microcalorimetry has been employed to study the interaction of ethylene with the reduced and oxidized Pt-Ag/SiO2catalysts with different Ag contents to elucidate the modified effect of Ag towards the hydrocarbon processing on platinum
catalysts. In addition, microcalorimetric adsorption of H2, O2, CO and FTIR of CO adsorption were conducted to investigate the influence of Ag on the surface structure of Pt catalyst.
It is found from the microcalorimetric results of H2and O2adsorption that the addition of Ag to Pt/SiO2leads to the enrichment of Ag on the catalyst surface which decreases the size of Pt surface ensembles of Pt-Ag/SiO2catalysts. The microcalorimetry and FTIR of CO adsorption indicates that there still exist sites for linear and bridged CO
adsorption on the surface of platinum catalysts simultaneously although Ag was incorporated into Pt/SiO2. The ethylene microcalorimetric results show that the decrease of ensemble size of Pt surface sites suppresses the formation
of dissociative species (ethylidyne) upon the chemisorption of C2H4on Pt-Ag/SiO2. The differential heat vs. uptake plots for C2H4adsorption on the oxygen-preadsorbed Pt/SiO2and Pt-Ag/SiO2catalysts suggest that the incorporation of Ag to Pt/SiO2could decrease the ability for the oxidation of C2H4.
We report the optical absorption characteristics of highly porous, polycrystalline TiO2electrodes and the influence of hydrolysis period for the preparation processes by photoacoustic (PA) spectroscopy together
with photoelectrochemical (PEC) current ones. The PA spectra show peaks which are attributed to the lowest transition energy
due to the quantum confinement effect. The peak intensity decreases with the increase of hydrolysis periods, indicating the
possibilities of the changes in the thermal properties and the densities due to hydrolysis processes. The PEC spectra indicate
that the photocurrent intensity also show peak and that of the longer hydrolysis periods is somewhat smaller than others,
indicating the increase of interface states due to the formation of grain boundaries with the increase of hydrolysis processes.
A 18-mer partial phosphorothioate oligonucleotide sequence was synthesized and grafted in 5′ with a tyramine group which was
further radioiodinated. The Namalwa (VH 1 family) and HL-60 cell lines were transducted with liposome-mediated 125I-FR1-ASON. Liposome-mediated 131I-FR1-ASON and 131I labeled sense oligonucleotides were injected intratumorally into tumor-bearing BALB/c mice (6 weeks after inoculation of
107 Namalwa cells). Biodistribution was monitored by sequential scintigraphy and organ radioactivity measurement at 24 hours
after injection. The transduction efficiency in Namalwa cell lines reached (26.8±1.54)% that was higher than HL-60 cell lines.
Antisense probe images show tracer accumulation in tumor.