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  • Author or Editor: Jianfei Ding x
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Abstract

The dehydrogenation of isobutane to produce isobutene coupled with reverse water gas shift (RWGS) reaction in the presence of carbon dioxide was investigated over a NiO/γ-Al2O3 catalyst. The results illustrated that the coupling dehydrogenation of isobutane in carbon dioxide over NiO/γ-Al2O3 catalyst is effective, and the NiO/Al2O3 catalyst was modified with deposited carbon by impregnation of alumina with an aqueous solution of Ni(H2NCH2CH2NH2)x (NO3)2. Carbon modification can decrease the total acidity of the NiO/γ-Al2O3 catalyst and enhance the dispersion of NiO active phase. Furthermore, carbon has low acidity and anti-coking performance, so the carbon modification is effective in suppressing the coke formation and side reactions occurrence. Therefore, the catalyst stability and the isobutene selectivity are improved significantly by the carbon modification.

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Abstract

The catalytic hydrogenation of p-nitrophenol to produce p-aminophenol (PAP) was carried out over the catalyst nickel supported on active carbon (AC). The calcination temperature was one of the most important technical conditions: temperature higher than 450 °C would result in the reduction of NiO to Ni phase by AC and the loss of support. The surface area and nickel dispersion over catalyst decreased obviously after 450 °C calcination temperature because of the loss of support and the Ni phase sintering. Addition of K2O enhanced the alkalinity of the Ni/AC catalyst, and the p-nitrophenol stuff performed rather stronger acidity. Therefore, the level of p-nitrophenol adsorption over Ni/AC catalyst was improved, and the reaction efficiency was enhanced consequently. The p-nitrophenol conversion and PAP selectivity reached 97.7 and 99.3% over Ni–K2O/AC catalyst, respectively. During the process of catalytic hydrogenation, higher PAP selectivity was kept successively. It indicated that no side reactions happened during the catalytic hydrogenation of p-nitrophenol.

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