Thermal decomposition of N,N′-diphenylguanidine (DPG) was investigated by simultaneous TG/DSC-FTIR techniques under nonisothermal conditions. Online FTIR measurements illustrate that aniline is a major product of DPG decomposition. The observation that the activation energy depends on the extent of conversion indicates that the DPG decomposition kinetics features multiple processes. The initial elimination of aniline from DPG involves two pathways because of the isomerization of DPG. Mass spectrometry and thin film chromatography suggest that there are two major intermediate products with the major one of C21N3H17. The most probable kinetic model deduced through multivariate nonlinear regression method agrees well with the experimental data with a correlation coefficient of 0.9998. The temperature-independent function of conversion f(α), activation energy E and the pre-exponential factor A of DPG decomposition was also established through model-fitting method in this research.
Authors:B. Hu, Y. Song, L. Wang, Q. Zhang, J. Li, K. Wei, Y. Chen, and L. Zhang
Electronic stopping power of 19F in Ni, Pd and Gd was measured and compared to Mstar and SRIM calculation as well as experimental results published in literature.
It turns out that the present electronic stopping power agrees reasonably well with them.
Authors:X.L. Qi, X.F. Li, F. He, L.Q. Hu, Y.G. Bao, J.R. Gao, and H.G. Wang
Thinopyrum intermedium, which has many useful traits, is valuable for wheat breeding. A new wheat-Thinopyrum addition line, SN100109, was developed from the progeny of common wheat cultivar Yannong 15 and Th. intermedium. It was resistant to most races of Blumeria graminis f. sp tritici (Bgt), which caused powdery mildew in wheat, and its reactions were different from the reactions of gene Pm40 and Pm43. Genomic in situ hybridization (GISH) and molecular marker analysis were used to identify the genomic composition of SN100109. GISH results showed that SN100109 was a wheat-Th. intermedium disomic addition line containing one pair of J chromosomes, and the resistance gene was located on the alien additional chromosomes of SN100109. And four molecular markers BE425942, BF482714, Xgdm93 and BV679214 which were assigned to homologous group 2, were specific molecular markers of the additional chromosomes. All the results indicated that SN100109 contained one pair of 2J chromosomes. SN100109 can be used as a novel germplasm source for introducing powdery mildew resistance genes to wheat in breeding programs.
Biofortifying food crops with essential minerals would help to alleviate mineral deficiencies in humans. Detection of quantitative trait loci (QTLs) for mineral nutrient contents in rice was conducted using backcross inbred lines derived from an interspecific cross of Oryza sativa × O. rufipogon. The population was grown in Hangzhou and Lingshui, with the contents of Mg, Zn, Fe, Mn, Cu and Se in brown rice measured in both trials and that in milled rice tested in Hangzhou only. A total of 24 QTLs for mineral element contents were identified, including two for both the brown and milled rice, 17 for brown rice only, and five for milled rice only. All the seven QTLs detected for the mineral contents in milled rice and 13 of the 19 QTLs for the contents in brown rice had the enhancing alleles derived from O. rufipogon. Fifteen QTLs were clustered in seven chromosomal regions, indicating that common genetic-physiological mechanisms were involved for different mineral nutrients and the beneficial alleles could be utilized to improve grain nutritional quality by markerassisted selection.
Authors:H. X. Ma, B. Yan, Y. H. Ren, Y. Hu, Y. L. Guan, F. Q. Zhao, J. R. Song, and R. Z. Hu
3,3-Dinitroazetidinium (DNAZ) salt of perchloric acid (DNAZ·HClO4) was prepared, it was characterized by the elemental analysis, IR, NMR, and a X-ray diffractometer. The thermal behavior and decomposition reaction kinetics of DNAZ·HClO4 were investigated under a non-isothermal condition by DSC and TG/DTG techniques. The results show that the thermal decomposition process of DNAZ·HClO4 has two mass loss stages. The kinetic model function in differential form, the value of apparent activation energy (Ea) and pre-exponential factor (A) of the exothermic decomposition reaction of DNAZ·HClO4 are f(α) = (1 − α)−1/2, 156.47 kJ mol−1, and 1015.12 s−1, respectively. The critical temperature of thermal explosion is 188.5 °C. The values of ΔS≠, ΔH≠, and ΔG≠of this reaction are 42.26 J mol−1 K−1, 154.44 kJ mol−1, and 135.42 kJ mol−1, respectively. The specific heat capacity of DNAZ·HClO4 was determined with a continuous Cp mode of microcalorimeter. Using the relationship between Cp and T and the thermal decomposition parameters, the time of the thermal decomposition from initiation to thermal explosion (adiabatic time-to-explosion) was evaluated as 14.2 s.
Authors:S.-C. Ye, L.-Y. Hu, K.-D. Hu, Y.-H. Li, H. Yan, X.-Q. Zhang, and H. Zhang
Hydrogen sulfide (H2S) has been recently found to be a gaseous signaling molecule in plants. In this work, we studied the role of H2S in alleviating salinity stress during wheat grain germination (Triticum aestivum L. Yangmai 158). Pretreatment with NaHS, a H2S donor, during wheat grain imbibition, could significantly attenuate the inhibitory effect of salinity stress on wheat germination. NaHS-pretreated grain showed higher amylase and esterase activities than water control. NaHS pretreatment differentially stimulated the activities of catalase (CAT), guaiacol peroxidase (POD) and ascorbate peroxidase (APX), decreased the level of malondialdehyde (MDA) and reduced NaCl-induced changes in plasma membrane integrity in the radicle tips of seedlings compared with water control. We conclude that H2S plays an important role in protecting wheat grain from oxidative damage induced by salinity stress.