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  • Author or Editor: M. R. Weber x
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Доказывается, что в ар химедовой векторной структуреX для того, чтобы каждый финитный элем ент являлся также тот ально финитным, достаточно, чтобы топология в подпрост ранствеM Φ пространст ва всех максимальныхl-идеало вM векторной структурыX обладала тем свойст вом, что замыкание (вM) счетно го объединения базисны х множеств лежитвM Φ.

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Abstract  

The formation of cationic astatine /I/-coordination compounds with selenium-containing neutral ligands is described. The detection of compound formation and first physico-chemical data on the characterization of this new group of At/I/-compounds were obtained by investigation of their electromigration behaviour in free electrolytes. Se-donors coordinate more strongly to At/I/ than ligands containing carbamide and thiocarbamide. This fact is proved by electromigrational studies on the exchange of N,N-ethyleneselenocarbamide, respectively N,N-ethylenethiocarbamide with iodide.

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Journal of Radioanalytical and Nuclear Chemistry
Authors: A. Türler, H. Gäggeler, K. Gregorich, H. Barth, W. Brüchle, K. Czerwinski, M. Gober, N. Hannink, R. Henderson, D. Hoffman, D. Jost, C. Kacher, B. Kadkhodayan, J. Kovacs, J. Kratz, S. Kreek, D. Lee, J. Leyba, M. Nurmia, M. Schädel, U. Scherer, Schimpf, D. Vermeulen, A. Weber, H. Zimmermann, and I. Zvara

Abstract  

On-line isothermal gas phase chromatography was used to study halides of261104 (T1/2=65 s) and262,263105 (T1/2=34 s and 27 s) produced an atom-at-a time via the reactions248Cm(18O, 5n) and249Bk(18O, 5n, 4n), respectively. Using HBr and HCl gas as halogenating agents, we were able to produce volatile bromides and chlorides of the above mentioned elements and study their behavior compared to their lighter homologs in Groups 4 or 5 of the periodic table. Element 104 formed more volatile bromide than its homolog Hf. In contrast, element 105 bromides were found to be less volatile than the bromides of the group 5 elements Nb and Ta. Both 104 and Hf chlorides were observed to be more volatile than their respective bromides.

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