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Abstract  

The isotopic exchange rate of thiourea in hexa(thiourea) plumbous nitrate was determined at two different concentrations. The results showed that the complex is unstable in the kinetic sense. The rate of exchange increases with increase of concentration of the free ligand and also of the complex. Furthermore, the results indicated that an increase in temperature by 15°C does not influence the rate to any significant degree.

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Abstract  

Cadmium in water was preconcentrated by adsorption on activated carbon after complexation with potassium ethyl xanthate. The recovery was >90% in the concentration range 10 g l–1 to 500 g l–1 with an enrichment factor of 1000. The method was employed for the analysis of cadmium in spiked water samples, by NAA and AAS. The standard deviation and relative mean error was 0.062 and 0.015, respectively.

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Abstract  

Silver from aqueous solution was preconcentrated by adsorption on activated carbon as silver xanthate. Factors influencing the adsorption of silver have been studied. Optimum conditions for the preconcentration of silver have been established.

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Abstract  

Metal exchange behaviour of tris/diethyl dithiocarbamate/ chromium/III/ complex has been studied at 25°C and 35°C varying the concentration of the metal ion and the complex. Experimental observation showed that the complex is kinetically labile. Temperature and concentration increase, increases the rate of reaction.

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Abstract  

Isotope exchange behaviour of bis/diethyl dithiocarbamate/ copper/II/ complex has been studied at 30 °C and 40 °C varying the concentration of the complex and metal ion. Results indicate that the complex is labile in chloroform dimethyl sulphoxide medium. Increase in concentration has significant effect on the rate of the reaction. Similarly the increase in temperature increased the rate of the reaction.

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Abstract  

Isotope exchange behaviour of bis/diethyl dithio carbamate/cadmium/II/ complex has been studied at 25°C and 35°C varying the concentrations of both metal ion and the complex. The results show that the complex is kinetically labile and the concentration has a significant effect on the rate of the reaction. Increase in temperature also effects the rate of exchange.

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Abstract  

Isotope exchange behaviour of bis/diethyldithiocarbamate/mercury/II/ complex has been studied at 25°C and 45°C varying the concentrations of both metal ion and the complex. The results show that the complex is kinetically labile. Temperature has a significant effect on the rate of the reaction. Increase in concentration increases the reaction rate.

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Study on curing of novolac epoxy resin

Polyamide hardener systems

Journal of Thermal Analysis and Calorimetry
Authors: J. P. Agrawal, N. M. Bhide, and S. R. Naidu

The optimization of proportions of novolac epoxy resin, Dobeckot E4 and polyamide hardener, EH411 has been established by DSC and the data indicates that resin-polyamide, 100∶40 and 100∶50, appear to be optimum where ‘extent of cure’ is maximum. The kinetic parameters for these formulations have been evaluated using isothermal and dynamic modes by employing DSC.

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Abstract  

Isotope exchange behavior of bis-resacetophenone phenylhydrazone) nickel(II) complex with nickel(II) in tri-n-butyl phosphate and methanol medium has been studied. The studies were carried out at different temperatures varying the concentration of both metal ion and the complex. The results show that the complex is labile in the kinetic sense. Increase in temperature increases the isotope exchange rate. The increase in concentration also results in an enhancement of the rate of reaction.

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Abstract  

Isotopic exchange behaviour of bis(diethyldithio carbamate) nickel(II) complex with nickel(II) in chloroform and methanol medium was studied. The studies were carried out at different temperatures varying the concentration of both metal ion and the complex. The results show that the complex is labile in the kinetic sense. Increase in temperature increases the isotopic exchange rate. The increase in concentration also results in enhancement of the rate of reaction.

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