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- Author or Editor: P. Sun x
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Abstract
In this paper the existence of positive solutions are obtained for a class of second order differential equations. The proof is based on the fixed point index theory in cones.
A novel multi-walled carbon nanotubes (MWCNTs) dispersive solid phase extraction (d-SPE) method which combined with gas chromatography (GC) coupled with electron capture detector (ECD) was developed for the determination of five pyrethroid pesticides in liquid milk for the first time. The effect of d-SPE conditions on the kinds of sorbent, MWCNTs and magnesium sulfate anhydro mass ratio, and extraction condition were researched, and then, the suitable method was found. Under the optimal conditions, the linear range was from 20 to 500 μg kg−1. The recoveries were from 81.8% to 112.1%, with the corresponding relative standard deviations (RSDs) less than 6%, correlation coefficients from 0.9978 to 0.9990, and limits of detection and quantification from 2.62 to 4.86 μg kg−1 and 8.73 to 16.2 μg kg−1. The proposed method is simple, fast, safe, and has high recovery and sensitivity applicable to analyze pyrethroid pesticides in liquid milk sample.
Abstract
The present study explores the feasibility of the determination of phosphorus at the extreme trace levels in high-purity silicon by radioreagent method. After silicon dissolution with hydrofluoric and nitric acids and matrix volatilization, 12-molybdophosphoric acid (12-MPA) is formed by the addition of the radioreagent,99MoO 4 2– , in nitric acid medium and then extracted into isobutyl acetate. By plotting the phosphorus content against the radioactivity of99Mo in the organic phase, a linear relationship persisting down to 5 ng is obtained. Special effort has been made to the elimination of the unreacted99MoO 4 2– reagent and the optimal control of phosphorus blank introduced through the multistage analytical procedure in order to ensure reliable determination of phosphorus at the ppb level.
This study is to explore the effect of ALAD polymorphism on hematopoietic, hepatic and renal toxicity from lead in occupational exposure workers
Abstract
The method of high-temperature hydrolysis separating fluorine from UF4 is described. The determination of the content of fluorine by different methods is performed and compared.
Abstract
The heat capacities of berberine sulphate [(C20H18NO4)2SO43H2O] were measured from 80 to 390 K by means of an automated adiabatic calorimeter. Smoothed heat capacities, H T-H 298.15 and S T-S 298.15 were calculated. The loss of crystalline water started at about 339.30.2 K, and its peak temperature was 365.80.6 K. The peak temperature of decomposition for berberine sulphate was at about 391.40.4 K by DSC curve. TG-DTG analysis of this material was carried out in temperature range from 310 to 970 K. TG and DSC curves show that there is no melting in the whole heating process.
Abstract
A solid complex of rare-earth compounds with alanine, [ErY(Ala)4(H2O)8](ClO4)6 (Ala=alanine), was synthesized, and a calorimetric study and thermal analysis for it was performed through adiabatic calorimetry and thermogravimetry. The low-temperature heat capacity of [ErY(Ala)4(H2O)8](ClO4)6 was measured with an automated adiabatic precision calorimeter over the temperature range from 78 to 377 K. A solid-solid phase transition was found between 99 and 121 K with a peak temperature at 115.78 k. The enthalpy and entropy of the phase transition was determined to be 1.957 Kj mol-1, 16.90 j mol-1 k-1, respectively. Thermal decomposition of the complex was investigated in the temperature range of 40~550C by use of the thermogravimetric and differential thermogravimetric (TG/DTG) analysis techniques. The TG/DTG curves showed that the decomposition started from 120 and ended at 430C, completed in three steps. A possible mechanism of the thermal decomposition was elucidated.
Abstract
A microcalorimetric technique based on the bacterial heat-output was explored to evaluate the effect of Mn(II) on Bacillus thuringiensis. The power-time curves of the growth metabolism of B. thuringiensis and the effect of Mn(II) on it were studied using an LKB-2277 BioActivity Monitor, ampoules method, at 28C. For evaluation of the results, the maximum peak-heat output power (P max) in the growth phase, the growth rate constants (k), the log phase heat effects (Q log ), and the total heat effect in 23 h (Q T) for B. thuringiensis were determined. Manganese has been regarded as the essential biological trace element. Mn(II) of different concentration have different effects on B. thuringiensis growth metabolism. High concentration (800-1600 μg mL-1) of Mn(II) can promote the growth of B. thuringiensis; low concentration (500-800 μg mL-1) can inhabit its growth.
Influence of different maturity stages and treatments of ethephon, exogenous ABA, and fluridone on the ripening and hormone level of ‘Zhonghuashoutao’ peach during development and post-harvest storage were investigated. The accumulation of endogenous ABA appeared at the onset of ripening and peaked at two weeks before harvest. Fruit firmness decreased, while ethylene release and SSC/TA increased sharply after a maximum peak of ABA, which have triggered the initiation of the fruit ripening. The fruits, harvested at 170 d when fruits have ripened and stored at 20 °C, showed an ethylene climacteric peak, and the pulp started softening normally, and the SSC/TA value increased. Compared with them, the immature green fruits harvested at other dates, could not mature normally due to the lack of normal reciprocity between ABA and ethylene. The ethylene release was promoted by the treatment of exogenous ABA and ethephon during ripening until the endogenous ABA reached a maximum value. However, fluridone treatment showed an inhibitory effect. The above-mentioned changes occurred again in the peach fruits after harvest. The results indicated that both ABA and ethylene play important roles in peach ripening, and their action depended on the ripening stage of peach.
