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Representation T-V-x des systemes binaires a tension de vapeur non negligeable

III. — Etude expérimentale par ATD du système NdAs-As

Journal of Thermal Analysis and Calorimetry
Authors: J. C. Rouland, C. Souleau, and R. Ceolin

The effect of the variableV/m on the appearance of DTA endotherms has been used to obtain quantitative data on theT-V-x representation of the NdAs-As system.

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Abstract  

Measurements of the masses of incorporated water and of the heats of hydration have been performed at 310 K, under air atmosphere saturated with water vapour, on three differently dehydrated samples of the Saccharomyces boulardii yeast in order to evaluate differences in physicochemical properties related to the following dehydration processes: cryodesiccation (or lyophilization) and thermodesiccation (spray drying and in-fluidized-bed heating).Thermogravimetric (TG) experiments have shown that the lyophilized yeast contains less residual water than heat-treated yeasts and that it incorporates more water and more rapidly. Isothermal water sorption of a spherical yeast cell has been represented by a two-parameter equation able to take account of a maximum of the hydration rate when this is taken as a function of time. On the other hand, isothermal DSC experiments have shown that hydration-heat values are higher for the heat-treated yeasts than for the lyophilized one. The TG and DSC results have been shown to be consistent with the idea that the physicochemical properties of a dehydrated yeast are related to cell-wall behaviour during desiccation.

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Journal of Thermal Analysis and Calorimetry
Authors: J. Rouland, C. Souleau, and R. Céolin
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RepresentationT-V-x des systemes binaires a tension de vapeur non negligeable

I. Règle des phases, règle du levier et description d'un équilibre eutectique

Journal of Thermal Analysis and Calorimetry
Authors: J. Rouand, C. Souleau, and R. Ceolin

Binary systems with non-negligible vapour pressure may be described by theT-V-x diagram. The use of the volumeV as an independent variable makes it possible to show the part played by the vapour phase in binary systems. This first part deals with the experimental connection betweenT, V andx data measured by DTA with sealed silica ampoules. As an example the eutectic composition is used: the theoretical isothermal, isochoric and isoplethal sections are presented and compared to those of some former works.

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