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- Author or Editor: R. Grzybek x
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Abstract
The [MoOC1(dppe)2]Cl complex [dppe=(C6H6)2P(CH2)2 P(C6H5)2] was successfully examined in a process of reduction of molecular nitrogen in -radiation field. Yields of ammonia produced in this process were measured as a function of the Mo(IV) complex concentration and dose.
Abstract
The molybdenum hydrazido complex [Mo(NHH2)(HSO4)(dppe)2]HSO4 was used in the process of fixation and reduction of molecular nitrogen in -radiation field. This process has been found as a catalytic one. Results of this work generally confirm conclusions of the previous works and some new aspects of the mechanism of this process are discussed.