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  • Author or Editor: R. Sassoulas x
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The solid ⇌ solid equilibria in the binary system Ca3(PO4)2-CaNaPO4 have been studied. Different diagrams have been proposed for this system. The differences relate to the limits of the field of existence of a non-stoichiometric phase (phase A) stable at high temperature and undergoing eutectoid decomposition during cooling; they can be explained by the existence of two metastable equilibria diagrams which are superposed in the stable diagram. These metastabilities depend on both the cooling rates and the maximum temperatures reached before this cooling.

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