In the present study the crustal structures of Nile Delta, including Greater Cairo province, and its surroundings, were evaluated using 3D forward gravity and magnetic modeling. The interpretation is also based on the seismic reflection results, well logs data and previous density models. The present results allow to improve the understanding of both the crustal thicknesses and density distributions between the sedimentary cover and the upper mantle in the study area.The high Bouguer anomalies near the Mediterranean coast are mainly caused by deep-seated structures. The crust beneath the Mediterranean coastal region is typically continental, with a thickness of 24 km beneath Rositta and Damitta branches, which increases toward the south. The Greater Cairo province has been modeled with maximum crustal thickness of ca. 34 km. The negative gravity anomalies with minimum values are due to the effect of sedimentary cover and/or basement relief geometry.The main results of this work suggest that the study area could be divided into three different distinctive tectonic zones according to their Moho depth and crustal structures. The southern zone (unstable shelf zone) which covers the Greater Cairo province is characterized by maximum crustal modeled thickness. It also represents the most seismically active tectonic zone in the study area. On the contrary the middle and northern zones show a thinned crustal layer and a correspondingly thicker sedimentary cover.Furthermore, the magnetic anomalies along the Greater Cairo, as deduced from the 3D magnetic modeling, are mainly caused by the upper crustal structures. In particular, the high magnetic anomalies of the southern part of the studied area are interpreted as related to variation in the basement relief near the surface, resulting from block faulting and/or compressional folds.In the northern region near the Mediterranean coastal area the highest magnetic susceptibility anomaly values is affected by the shallow smooth relief of the lower crustal layer. Finally, limited, shallow-seated basaltic intrusions were modeled beneath the western side of Nile Delta. The existence of these basaltic intrusions suggests that the study area was influenced by the opening of the Red Sea and/or Gulf of Suez during the Oligocene time.
Three-dimensional gravity modeling has been performed for the Eastern Mediterranean including the northeastern Egyptian off-shore area. The gravity models and seismic profiles indicate that a transition from two layer continental crust to a simple layer oceanic crust takes a place along the Levantine margin. The transition along three profiles is located beyond the north African continental margin and it is quite gradual. The crust under the Levantine basin is typically oceanic and slightly thin with 13 km thickness, however it is typical continental under the Egyptian off-shore and having 30 km thickness. The obtained results reflect a large sedimentary sequence of 14 km under the Levantine basin. Since the sediments recovered by the Oceanic Drilling Program Leg160 in the eastern Mediterranean ranged from Pleistocene to Cretaceous, this reflects fairly high sedimentation rate. Distribution of recent earthquake foci indicates that almost all earthquakes occurred along the western and central segments of the Cyprean arc while they completely disappear along the eastern segment. This means that collision between Cyprus and the Eratosthenes seamount is marked by seismic activity and clearly affects the shape of the Cyprean arc. This collision represents a transition zone between active compression and probable subduction in the western segment and diffuse transtension through the eastern part of the arc. Incipient collision between Cyprus and Eratosthenes seamount probably began in Pleistocene time.
Crushing or otherwise processing potato and subsequent mild washing of the pulp produces mostly granular and fibrous starch.
These fibers are experimental carrier material for microbes in bioremediation of polluted waters. This method offers the benefit
of increasing the exposure of the microbes to the pollutant by increasing their residency within the site. Because of the
physical nature of the material, it also offers the possibility of carrying, in addition to the microbes, essential macronutrients
such as nitrogen and phosphorous that would be limited in availability in contaminated waters. We have previously reported
on the physical nature of these fibers through thermal analysis and on their ability to bind/aggregate bacteria. We have extended
that study in this report by infusing the fibers with a source of nitrogen and phosphorous, namely ammonium phosphate. The
TG curves for ammonium phosphate-infused white and sweet potato fibers exhibited three main mass loss steps corresponding
to the three exothermic DTG peaks. Infusion with the ammonium phosphate salt also affected the bacterial binding/aggregation
capacities. The range of their binding capacities decreased to a range of 26.9–43.3% compared to untreated fibers.
For the determination of cadmium in sea water, a neutron activation analysis method involving a preconcentration step has
been developed. Preconcentration is achieved by co-precipitation of cadmium dibenzyldithiocarbamate with phenolphthalein.
The precipitate is collected on 0.45 μm membrane filters and cadmium is determined by instrumental neutron activation analysis.
A115mCd radio tracer was used to establish optimum conditions and to evaluate the chemical yield.
Authors:S. Kandil, H. Hanafi, H. Aglan, and Z. Saleh
The adsorption behaviour of La/Ce system on Dowex 50W-X8 in different media, namely, nitric acid, acetate buffer and citrate
buffer was studied as a function of the concentration of nitric acid and buffer pH. In addition, in cation-exchange column
chromatography experiments, three different eluants, namely, citrate buffer of pH 5.5, 0.1 M EDTA and 0.2 M α-HIBA, were employed
for separation of Ce(III) from La(III). The optimum conditions for improvement of radiochemical separation of no-carrier-added
139Ce from proton irradiated lanthanum were applied using the most suitable chelating agent 0.2 M α-HIBA. The purification of
139Ce from macro amount of La(III) was done using two columns in a sequence. The target was prepared by pressing. The production
of high radionuclidic and chemical purity 139Ce via irradiation of lanthanum oxide target at MGC-20 cyclotron of proton energy 14.5 MeV was described. The experimental
yield was found to be 200 kBq/μA h.
Authors:E. Metwally, A. Saleh, S. Abdel-Wahaab, and H. El-Naggar
The diamide N,N,N′,N′-tetraoctyldiglycolamide (TODGA) was synthesized and characterized. The prepared TODGA was applied for extraction of Ce(III)
from nitric acid solutions. The equilibrium studies included the dependencies of cerium distribution ratio on nitric acid,
TODGA, nitrate ion, hydrogen ion and cerous ion concentrations. Analysis of the results indicates that the main extracted
species is Ce(TODGA)2(NO3)3HNO3. The capacity of Ce loading is approximately 45 mmol/L for 0.1 M solution of TODGA in n-hexane. Finally, the thermodynamic parameters were calculated: K (25 °C) = 3.8 × 103, ΔH = −36.7 ± 1.0 kJ/mol, ΔS = −54.6 ± 3.0 J/K mol, and ΔG = −20.4 ± 0.1 kJ/mol.
Authors:S. Kandil, R. Farag, Kh. Khalifa, and Z. Saleh
The adsorption behaviors of no-carrier-added radioiodine and a bulk of tellurium on the anion-exchange resin in different
media, namely, hydrochloric acid and sodium hydroxide solution were studied. The effect of shaking time on the uptake percentage
of the no-carrier-added radioiodine was carried out using the batch technique in both 7 M HCl and 8 M NaOH. In column experiments
for the separation of radioiodine from Te-bulk, different liquid phases such as, 2 M NaOH, 70 % methanol, a mixture of ethyl
acetate to ethanol (1:1 v/v) and 5 mM tetra-butyl ammonium bromide in ethyl acetate without and with few drops of 0.01 M sodium
metabisulfite were employed as eluants. Not only this, the bed depth of the resin was also taken into consideration. Different
weights of Amberlyst A-27 correspond to different bed depths (3, 4, 5, 6 cm) were employed. Under the optimum conditions the
overall radiochemical yield for the separated radioiodine was 90 % and recovery of Te-bulk was 98 %.
Authors:H. Aglan, S. Kandil, H. Hanafi, M. Mousa, and Z. Saleh
The radiochemical separation of no-carrier-added cerium from proton irradiated lanthanum was studied by solvent extraction
using DEE, TBP and TPPO, the latter reagent being employed for the first time for separation of radiocerium from bulk of lanthanum.
Distribution coefficients of cerium and lanthanum were investigated as a function of equilibrium time and concentration of
HNO3. A mixture of 0.05M K2Cr2O7 and 0.1M H2SO4 was used as an oxidizing agent to improve the separation efficiency of cerium. A comparative study of the three extractants
released that DEE is the best for separation of cerium from bulk of lanthanum oxide. The target was prepared by pressing.
The production of 139Ce of high radionuclidic purity and chemical purity via irradiation of lanthanum oxide target at MGC-20 cyclotron with protons
of energy 14.5 MeV is described. The experimental yield was found to be 153 kBq/μA·h.
Authors:H. Rathore, G. Varshney, S. Mojumdar, and M. Saleh
Zinc diethyldithiocarbamate, zinc diethyldithiocarbamate-phosphate and zinc phosphate have been synthesized. They have been
characterized using DTA-TG, IR spectra and X-ray. The dithiocarbamate and phosphate contents have been determined spectrophotometrically
and volumetrically, respectively. Fungicidal activity of the compounds has been tested by well diffusion method using fungi