Authors:M. Perraki, T. Perraki, K. Kolovos, S. Tsivilis, and G. Kakali
The sintering and hydration processes of a modified cement raw mix were examined using thermal analysis techniques. One reference
and four modified mixtures, prepared by mixing the reference sample with 0.5, 1.0, 1.5 and 2.0 % w/w of a wolframite-stibnite mineral were studied. The clinkering reactions were recorded and the total enthalpy change during
the sintering was determined by means of a differential scanning calorimetry. The combined water and the Ca(OH)2 content in samples hydrated for 1 to 28 days were determined, using thermogravimetry. As it is concluded, the effect of the
added mineral on the sintering and hydration reactions can be fully recorded and evaluated using thermal analysis.
Authors:E. Kontori, T. Perraki, S. Tsivilis, and G. Kakali
In this work, the hydration rate and products of blended zeolite cements were studied for periods up to 360 days. Thermoanalytical
methods (TG/DTG and DTA) were applied in order to evaluate the hydration rate of blended cements, while. X-ray diffraction
and FTIR spectroscopy were used in order to identify the hydrated products. As it is concluded the incorporation of zeolite
in cement contributes to the consumption of Ca(OH)2 formed during the cement hydration and the formation of cement-like hydrated products. The pozzolanic reaction of the zeolite
is rather slow during the first days of hydration but it is accelerated after the 28 days.