The adsorption behavior of silica gel for Zr, Pu and fission products (Fe, Mo, Nd, etc.) in high-level liquid waste (HLLW)
have been studied. The dynamic desorption for Zr and Pu are also investigated. Silica gel is found to have high selectivity
for Zr to other elements in HLLW and its adsorption capacity can be enhanced by H2C2O4 elution and multiple reuse. However, the adsorption for Pu(IV) is also found. This may cause spent silica gel to be alpha
waste. Further study should be carried out on the adsorption behavior for Pu(IV).
The feasibility of photon activation analysis (PAA) for river sediment has been demonstrated using a powerful linear electron accelerator at Rensselaer Polytechnic Institute. The sample was a standard sediment material (SRM 1646a Estuarine sediment) from NIST. Electron energy at 50 MeV and a tantalum target are used. Gamma-spectroscopy was performed with an HPGe detector. Sensitivities for Ca, Ti, As, Pb, Ce, Ni and Rb were obtained. The sensitivities were 14.7 µg for Ca, 21.5 µg for Ti, 0.9 µg for As, 3.9 µg for Pb, 1.1 µg for Ce, 1.6 µg for Ni and 3.5 µg for Rb. A large amount of Zr was found in SRM 1646a although it is not listed by NIST.
Authors:W. Huang, Y. Xu, X. Chen, X. Gao and Y. Fu
The radiation effect of γ-ray on polyether-urethane foam was studied. The gas products from irradiated samples were analyzed
quantitatively and qualitatively by gas chromatography, the thermal property and radical intensity were determined by differential
thermal gravimetry and electron spin resonance. The dynamic mechanical property, compression and tensile properties were analyzed.
Positron annihilation lifetime of irradiated samples was also measured at room temperature in vacuum. The results show that
the general mechanical properties of ETPU sample irradiated by γ-rays at a dose of 8.0·105 Gy is excellent, but there are considerable gas products and a great deal of radicals created, which indicates that the sample
has been damaged by radiation. Relatively, the thermal stability of the sample remained fine.
Authors:X. Li, X. Xu, X. Li, X. Yang, W. Liu and L. Li
A reborn interest has occurred during the last decade toward wheat landraces for broadening genetic basis of modern wheat cultivars. The investigation of molecular traits within and between existing landraces of wheat can help scientists to develop appropriate strategies for their efficient maintenance and exploitation. The present study dealt with the gliadin characterization of forty-seven wheat landraces collected from wheat mainly planted areas of China, each of which was represented by a sample of at least 43 individuals. Twelve accessions selected on the basis of gliadin analysis were investigated further using 21 SSR markers. The results proved that landraces of wheat are a mixture of variable individuals genetically distinguishable from each other. Twelve of the analyzed 47 accessions were observed to be homogeneous, while 35 (74.5%) of them were heterogeneous in their gliadin composition. In total, 122 gliadin pattern were observed. On average, 10.1% (Gst) of the total variation arose from differentiation among regions, and 89.9% was attributed to within-region variation. Furthermore, nineteen of the 21 SSR markers were polymorphic across all the populations. The total number of the amplified DNA products was 110, with a mean of 6.11 alleles per locus. The values of genetic diversity within each landrace population varied from 0.006 to 0.351. Implications for the management of this valuable genetic resource are discussed.
Authors:X. Li, X. Xu, X. Yang, X. Li, W. Liu, A. Gao and L. Li
Youzimai is a widespread wheat landrace and has been used extensively in breeding programs in China. In order to assess the genetic variation between and within Youzimai accessions, samples of 31 landrace accessions of wheat, all called ‘Youzimai’, were collected from 6 geographic regions in China and evaluated using morphological traits, seedling resistance to powdery mildew, gliadin and microsatellite markers. Typical differences among accessions were observed in morphological characteristics. Forty-five (58.4%) of 77 assayed SSR markers showed polymorphism over the entire collection and total 226 alleles were identified with an average of 5.02 alleles per locus. SSR data indicated that the accessions from Hebei province were the most diverse, as evidenced by greatest number of region-specific alleles and highest diversity index. These accessions, therefore, probably experienced the most substantial morphological and molecular evolution as a result of various natural and anthropomorphic influences. On the other hand, differentiation in gliadin phenotypes was found among seeds within 80.6% of total accessions and average 61.5% of entire collections showed heterogeneous and comprised resistant plants in reaction to powdery mildew, suggesting the presence of a wide diversity within the wheat landrace. By developing an intimate knowledge of the available wheat genotypes, appropriate selections can be made for commercial application in order to conserve and exploit the diversity of the wheat landraces.
Garlic is widely used as food flavouring, and China is the world's largest garlic producer and exporter. To develop a convenient technique for evaluation of garlic cultivars would be worthwhile, and it would have wide application in such a huge market. In this research, 3D front-face fluorescence data of 8 garlic cultivars were recorded, and independent component analysis was used to decompose the overall fluorescence spectra into six independent components. The first, second, and fourth independent components showed a big difference among the cultivars, and the chemical fluorophores behind these three components were specified as protein, vitamin B6, and ATP, respectively, as fluorescent markers for evaluation. The result showed that all 8 cultivars cluster separately. The cultivar “YNQJ” have the highest quality in terms of protein and vitamin B6, “NXYC” and “SDHB” have the highest content of ATP, while “SXXA” is the poorest in terms of protein and ATP, and “HNJZ” has the lowest content of vitamin B6. Therefore, rapid evaluation of garlic cultivars can be accomplished successfully by using only the proportion values of three properly selected fluorescent markers.
The production rates (numbers of atoms per gram of the respective elements per second) of 40 radioactive nuclides of 34 elements by neutron capture reactions in a reactor were determined from about 130 photopeaks of the -ray spectra. The ratios of these production rates were called R-matrix elements. These production rates and the respective thermal neutron capture cross sections were used to calculate the respective apparent neutron fluxes at the position of irradiation and the -matrix elements which were the ratios of these apparent neutron fluxes. These matrix elements express clearly the correlations among various elements and thus may be used in the mono-standard or small-number-standards method in neutron activation analysis.
Authors:S. Lahiri, X. Wu, Yang Weifan, Xu Yanbing and Yuan Shuanggui
Liquid liquid extraction of 46Sc was studied with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (PMBP). It has been found that PMBP extracts almost quantitatively scandium from 10-3 to 10-2M HCl solutions. Tributyl phosphate (TBP) has a pronounced antagonistic effect on the extraction process.
Authors:X. Zheng, T. Kawae, S. Tanaka, M. Suzuki and C. Xu
Heat capacity measurements were carried out on single-crystalline CuO in the temperature range 130–300 K. Sharp peaks corresponding to the antiferromagnetic transitions were clearly observed at 211 and 227 K. At the low-temperature end, near 160 K, a wide peak in the heat capacity signal was also demonstrated. An electric anomaly was observed in the temperature range 150–160 K, which strongly suggests the possibility of a new low-temperature phase transition in CuO. This study also indicates that DSC measurement is an effective tool to detect magnetic transitions and probe subtle phase transitions in solids.
Authors:J. Liu, H. Xu, W. Shen, X. Pan and Y. Xiang
Mn2O3/-Al2O3 catalysts were prepared by the impregnation method, and the maximum monolayer dispersion capacity or dispersion threshold value of Mn2O3 on the surface of -Al2O3 was determined to be 13.08% from the decomposition mass loss of supported Mn(NO3)2 in the monolayer state. This was compared with the values estimated from a close-packed monolayer model and an interaction model. It was confirmed that the high activities and selectivities of the catalysts for benzoic acid hydrogenation to benzaldehyde are due to the monolayer dispersion of the Mn2O3 on the surface of -Al2O3.