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Journal of Radioanalytical and Nuclear Chemistry
Authors: W. Sato, K. Sueki, K. Kikuchi, K. Kobayashi, S. Suzuki, Y. Achiba, H. Nakahara, Y. Ohkubo, F. Ambe, and K. Asai

Abstract  

Time-differential perturbed angular correlation method was applied to Ce@C82 in order to investigate the electronic properties of the encaged Ce atom. The nuclear quadrupole frequency of the nuclear spin of the Ce was successfully determined as ωQ = 6.5(3)·107 rad/s, which is much greater than what has already been estimated for Ce4+ and La3+ in other compounds. By comparing the present value with the values for the Ce4+ and La3+, it was inferred that the valence state of the encaged Ce atom is trivalent.

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Journal of Radioanalytical and Nuclear Chemistry
Authors: K. Kobayashi, M. Kuwano, K. Sueki, K. Kikuchi, Y. Achiba, H. Nakahara, N. Kananishi, M. Watanabe, and K. Tomura

Abstract  

Advantages and uniqueness of radiochemical techniques in fullerene studies are pointed out. Some experimental data are presented on metallofullerenes production yields, HPLC elution behaviors of Y, La, Gd containing fullerenes, encapsulation of a new metal in the carbon cage, stability of the carbon cage against recoil energy, and the distribution of metallofullerenes among various organs of rats.

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