Search Results
You are looking at 1 - 3 of 3 items for
- Author or Editor: Y. Teramoto x
- Refine by Access: All Content x
Abstract
In dealing with phenomena which show a linear response such as viscoelastic or dielectric properties, measurements are carried out by observing the relationship between the stimulus applied to the sample and the response from the sample. Since the Fourier analysis technique is effective in obtaining this relationship, two types of circuitries based on Fourier analysis have been created. Both DMA and dielectric measurement were used to evaluate these circuitries. Results were satisfactory, especially with respect to tanδ precision.
Abstract
An attempt to estimate the thermal decomposition mechanism of polymers using the simultaneous TG-DTA/FT-IR system was summarized. The library search of FT-IR spectra at various temperatures and of the subtraction spectrum obtained by subtracting the spectra at different temperatures were used to determine the types of evolved gases from poly(ethylene terephthalate) and poly(butylene terephthalate) at given stages of decomposition. The quantitative analysis of evolved gases was carried out using the specific gas profiles at the specific absorption band. The kinetic parameters were estimated from both TG and spectroscopic curves measured at various heating rates.
A combination system of thermogravimetric/differential thermal analysis (TG-DTA) and Fourier-transform infrared absorption spectroscopy (FT-IR) was described. This simultaneous TG-DTA/FT-IR technique gave spectroscopic and weight loss information about the thermal degradation process of engineering polyesters; poly(ethylene terephthalate)(PET) and poly(butylene terephthalate)(PBT). The evolved gases from PET were benzoic acid, carbon dioxide and carbon monoxide, while those from PBT were terephthalic acid esters and benzoic acid esters.
