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Abstract  

The contents of eight rare earth elements (La, Ce, Nd, Sm, Eu, Tb, Yb and Lu) in various plant species taken from a rare earth ore area were determined by instrumental neutron activation analysis. For a given plant, the REE patterns in root, leaf and host soil are different from each other. The REE distribution characteristics in roots of various species are very similar and resemble those in the surface water. The results of this study suggest that there is no significant fractionation between the REEs during their uptake by the plant roots from soil solution. However, the variation of the relative abundance of individual REE occurs in the process of transportation and deposition of REEs in plants.

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Abstract  

The principle for the electro-generative simultaneous leaching (EGSL) is applied to simultaneous leaching of pyrite-MnO2 in this paper. A galvanic system for the bio-electro-generative simultaneous leaching (BEGSL) has been set up. The equation of electric quantity vs. time is used to study the effect of produced sulfur on electro-generative efficiency and quantity. It has been shown that the resistance decreased in the presence of Acidithiobacillus thiooxidans (A. thiooxidans) with the increase of electro-generative efficiency. The effects of temperature and grain size on rate of ferrous extraction from pyrite under the conditions of presence and absence of A. thiooxidans were studied, respectively. The changes in the extraction rate of Fe2+ as particle size in presence of A. thiooxidans were more evident than that in the absence, which indicated that the extraction in bio-electro-generative leaching was affected by particle size remarkably. Around the optimum culture temperature for A. thiooxidans, the bigger change in the conversion rate of Fe2+ was depending on temperature. The transferred charge in BEGSL including part of S0 to sulfate group in the presence of (A. thiooxidans) which is called as biologic electric quantity, and the ratio of biologic electric quantity reached to 58.10% in 72 h among the all-transferred charge.

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Abstract  

Chemical behavior of lanthanum in root tips excized from wheat seedlings growing at both promotional and inhibitory levels of LaCl3 in culture solutions was investigated by a sequential leaching procedure combined with instrumental neutron activation analysis. The results indicate that most of La exists in non-exchangeable species and the binding of La3+ to the root tips is extremely stable. The root tips during growing at the inhibitory level of LaCl3 absorb much more La than those at the promotional level. However, the La proportion in each fraction is similar for both groups.

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Journal of Thermal Analysis and Calorimetry
Authors: Z. Xiao, D. Liu, C. Wang, Z. Cao, X. Zhan, Z. Yin, Q. Chen, H. Liu, F. Xu, and L. Sun

Abstract  

The effect of mechanical alloying on Zn-Sb alloy system is investigated with X-ray diffraction (XRD), laser grain size analysis and differential scanning calorimetry (DSC) respectively. The results of laser particle size analysis shows that the particle size decreases with increasing of the grinding time between 0 and 24 h. XRD and DSC results indicate that longer the grinding time of Zn-Sb is, the more content of Zn4Sb3 become in the product in this process.

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Uniformity in the height of main stem and tillers is a key factor affecting ideal plant type, a key component in super high-yielding rice breeding. An understanding of the genetic basis of the panicle layer uniformity may thus contribute to breeding varieties with good plant type and high yield. In the present study, a doubled haploid (DH) population, derived from a cross between indica rice variety Zhai-Ye-Qing 8 (ZYQ8) and japonica rice variety Jing-Xi 17 (JX17) was used to analyze quantitative trait loci (QTL) for panicle layer uniformity related traits. Six, four and three QTL were detected for the highest panicle height (HPH), lowest panicle height (LPH) and panicle layer dis-uniformity (PLD), respectively. qHPH-1-1 and qPLD-1 were located at the same interval on chromosome 1. The JX17 allele(s) of these QTL increased HPH and PLD by 2.57 and 1.26 cm, respectively. Similarly, qPLD-7 and qHPH-7 were located at the same interval on chromosome 7, where the ZYQ8 allele(s) increased HPH and PLD by 3.74 and 1.96 cm, respectively. These four QTL were unfavourable for panicle layer uniformity improvement because a decrease of the PLD was accompanied by decrease of the plant height. qPLD-6 and qLPH-6-1 were located at the same interval on chromosome 6, however here the JX17 allele(s) increased LPH, but decreased PLD, suggesting that this QTL was favourable for improvement of panicle layer uniformity. The markers identified in this study are potential for marker assisted breeding for the improvement of the panicle layer uniformity and ideal plant type.

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Abstract  

Chemical elemental compositions of some silicate, magnetic and glass spherules were investigated with INAA. The elements determined include Os, Ir, Ni, Co, Fe, Cr, Au, La, Ce, Sm, Eu, Yb, Lu and Sc etc. The elemental correlation, as well as their enrichment (or depletion) factors relative to Cl chondrite were examined. The high concentrations of the refractory siderophile elements contained in these spherules support the proposal that they originate from extraterrestrial substances. Some useful chemical criteria for identifying the sources of silicate, magnetic and glass spherules are put forward.

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Abstract  

Radiolabeled somatostatin analogue is a useful ligand for scintigraphic imaging of somatostatin receptor-bearing tumors. In this study, we investigated the effects of different radiolabeling conditions on labeling yield and ratio between mono-iodinated and di-iodinated125I-Tyr3-octreotide by HPLC analysis. In vitro and in vivo stabilities of125I-Tyr3-octreotide and111In-DTPA-D-Phe1-octreotide were also determined. Both radiolabeled compounds were relatively stable in vitro, but were decomposed to free125I− and111In-DTPA in vivo, respectively.

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Abstract  

A dual cell system was used to study the electrogenerative leaching sphalerite-MnO2 under the conditions of presence and absence of Acidithiobacillus ferrooxidans (A. ferrooxidans). The polarization of anode and cathode, and the relationship between the electric quantity (Q) and some factors, such as the dissolved Zn2+, Fe2+, the time in the bio-electro-generating simultaneous leaching (BEGSL) and electro-generating simultaneous leaching (EGSL), were studied. The results show that the dissolved Zn2+ in the presence of A. ferrooxidans is nearly 60% higher than that in the absence of A. ferrooxidans; the electrogenerative quantity in the former is about 134% more than that in the latter. A three-electrode system was applied to study anodic and cathodic self-corrosion current, which was inappreciable compared with the galvanic current between sphalerite and MnO2. The accumulated sulfur on the surface of sulfides produced in the electrogenerative leaching process could be oxidized in the presence of A. ferrooxidans, and the ratio of biological electric quantity reached to 31.72% in 72 h.

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Abstract  

The copper(II) complex of 6-benzylaminopurine (6-BAP) has been prepared with dihydrated cupric chloride and 6-benzylaminopurine. Infrared spectrum and thermal stabilities of the solid complex have been discussed. The constant-volume combustion energy, Δc U, has been determined as −12566.92±6.44 kJ mol−1 by a precise rotating-bomb calorimeter at 298.15 K. From the results and other auxiliary quantities, the standard molar enthalpy of combustion, Δc H m θ, and the standard molar of formation of the complex, Δf H m θ, were calculated as −12558.24±6.44 and −842.50±6.47 kJ mol−1, respectively.

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Abstract  

99Tc is an important radionuclides related to repository safety assessment. The mobility pertechnetate (TcO4 ) can be reduced to immobility technetium(IV) hydrous oxides (TcO2·nH2O) by Fe(II)-bearing minerals. In China, Gaomiaozi (GMZ) bentonite is regarded as the favorable candidate backfilling material for the HLW repository, which is contained some FeO. The diffusion behavior of 99Tc was investigated in GMZ bentonite by through- and out-diffusion methods. The effective diffusion coefficient (D e), the accessible porosity (εacc), apparent diffusion coefficient (D a) and distribution coefficient (K d) were decreased with the increasing of dry density. The D e values were (2.8 ± 0.2) × 10−11 m2/s and (3.5 ± 0.2) × 10−12 m2/s at dry density of 1,600 and 1,800 kg/m3, respectively. It was indicated that the dominating species was TcO4 during the diffusion processing. While, out-diffusion results showed that part of TcO4 may be reduced by Fe(II). The relationship of D e and εacc could be described by Archie’s law with exponent n = 2.4 for 99Tc diffusion in GMZ bentonite. Furthermore, the relationship between D a and dry density (ρ) was exponential.

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