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In order to measure 182Hf by accelerator mass spectrometry (AMS), a chemical procedure for separation of hafnium from tungsten has been developed by extraction chromatography. The extraction chromatographic behavior of hafnium and tungsten has been studied using tri-n-octylamine (TOA) as the stationary phase, HCl–H2O2 mixture and NH3·H2O as the mobile phase. The effects of H2O2 concentration, column loading and column dimensions are investigated. Hf and W with microgram amounts are successfully separated on a chromatographic column (Ø5 × 196 mm), on which Hf is hardly retained after completely eluted with 6 M HCl–1% H2O2 and W strongly adsorbed is then eluted with 3 M NH3·H2O. The decontamination factor for tungsten is 3.0 × 105 and the recovery of hafnium is better than 99% using a single column separation.

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