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Production of quinaldine and derivatives is proposed using sulfuric acid as commercial homogeneous acid catalyst in water in continuous flow chemistry. This approach is a rapid, practical and green route for the synthesis of 2-methylquinolines and permit to obtain the target compounds in 39–91% yields.

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H. Yalgin , D. Luart , C. Len “ First Examples of Doebner-Miller Reaction in Flow: Efficient Production of 2-Methylquinoline Derivatives in Water ” Journal of Flow Chemistry 2016 , 6 , 80 – 85

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