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Abstract  

The carboxylato–Cu(II) complexes of type [Cu2(RCOO)4] and their benzothiazole adducts [Cu2(RCOO)4bt2] (bt = benzothiazole, R = CH3(CH2)n−2, n = 12, 14, 16, 18) form the main objectives of this study. The studied carboxylato–Cu(II) complexes are formed from dimeric units to polymeric chains (chromofor CuO5). The structural changes are due to coordination of ligand (benzothiazole). The polymeric chains of carboxylato–Cu(II) complexes degraded to discrete centrosymetric tetracarboxylate-bridged dimmers (chromofor CuO4N). These prepared compounds [Cu2(RCOO)4] and [Cu2(RCOO)4L2] were submitted to measurements relating to spectral (IR, UV–Vis) and thermal properties (TG, DTA, DSC).

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-008-9188-7 . 19. Mojumdar , SC , Madhurambal , G , Saleh , MT . 2005 . A study on synthesis and thermal, spectral and biological properties of carboxylato-Mg(II) and carboxylato-Cu(II) complexes with bioactive ligands

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, Madgurambal , G , Saleh , MT 2005 A study on synthesis and thermal, spectral and biological properties of carboxylato-Mg(II) and carboxylato-Cu(II) complexes with bioactive ligands . J Therm Anal Calorim 81 : 205 – 210 10.1007/s10973

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