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Molar heat capacity and thermodynamic properties of crystalline Ho(Asp)Cl2·6H2O

Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 89: Issue 1
DOI:
https://doi.org/10.1007/s10973-005-7489-7
Authors: B. Liu, X. Lv, Z. Tan, Z. Zhang, Q. Shi, L. Yang, J. Xing, L. Sun, and T. Zhang

Abstract  

The molar heat capacity, C p,m, of a complex of holmium chloride coordinated with L-aspartic acid, Ho(Asp)Cl2·6H2O, was measured from 80 to 397 K with an automated adiabatic calorimeter. The thermodynamic functions H T-H 298.15 and S T-S 298.15 were derived from 80 to 395 K with temperature interval of 5 K. The thermal stability of the complex was investigated by differential scanning calorimeter (DSC) and thermogravimetric (TG) technique, and the mechanism of thermal decomposing of the complex was determined based on the structure and the thermal analysis experiment.

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Thermodynamic properties and molar heat capacity of Er2(Asp)2(Im)8(ClO4)6·10H2O

Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 103: Issue 3
DOI:
https://doi.org/10.1007/s10973-010-1218-6
Authors: X.-C. Lv, Z.-C. Tan, and X.-H. Gao

.1016/0277-5387(95)00575-7 . 7. Liu , B-P , Lv , X-C , Tan , Z-C , Zhang , Z-H , Shi , Q , Yang , L-N , Xing , J , Sun , L-X , Zhang , T 2007 Molar heat capacity and thermodynamic properties of crystalline Ho(Asp)Cl 2 ·6H 2 O . J

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