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Abstract  

Polyaniline/α-Al2O3 (PANI/α-Al2O3) composites were synthesized by in situ polymerization through ammonium persulfate ((NH4)2S2O8, APS) oxidized aniline using HCl as dopant. XRD and FTIR were used to characterize the PANI/α-Al2O3 composites. The thermal stabilities and glass transition temperature (T g) of PANI/α-Al2O3 composites were tested using thermogravimetric (TG) method and modulated differential scanning calorimetry (MDSC) technique. The results of TG showed that the thermal stability of PANI/α-Al2O3 composite increased and then decreased with the increase in α-Al2O3 content. The derivative thermogravimetry (DTG) curves showed one step degradation of PANI when the α-Al2O3 content was lower than 52.5 mass%, and exhibited two steps degradation when the α-Al2O3 content was higher than 63.6 mass%. The MDSC curves showed that the T g of PANI/α-Al2O3 composites increased and then decreased with the augment of α-Al2O3 for the interaction between PANI chains and the surface of α-Al2O3.

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-006-7569-3 . 7. Qi , YN , Xu , F , Sun , LX , Zeng , JL , Liu , YY . Thermal stability and glass transition behavior of PANI/α-Al 2 O 3 composites . J Therm Anal Calorim . 2008 ; 94 : 553 – 557 . 10.1007/s10973

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