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Abstract  

The complexes of [Sm(o-MOBA)3bipy]2·H2O and [Sm(m-MOBA)3bipy]2·H2O (o(m)-MOBA = o(m)-methoxybenzoic acid, bipy-2,2′-bipyridine) have been synthesized and characterized by elemental analysis, IR, UV, XRD and molar conductance, respectively. The thermal decomposition processes of the two complexes were studied by means of TG–DTG and IR techniques. The thermal decomposition kinetics of them were investigated from analysis of the TG and DTG curves by jointly using advanced double equal-double steps method and Starink method. The kinetic parameters (activation energy E and pre-exponential factor A) and thermodynamic parameters (ΔH , ΔG and ΔS ) of the second-step decomposition process for the two complexes were obtained, respectively.

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contain 8.5 molecules of water, cerium (III), and gadolinium (III) complexes are nonahydrated, while neodymium (III) complex ( Fig. 3 ) is octahydrated and samarium (III) complex contains 7.5 water molecules. Amount of water was determined from

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