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Modulated temperature differential scanning calorimetry

Characterization of curing systems by TTT and CHT diagrams

Journal of Thermal Analysis and Calorimetry
Authors: A. Van Hemelrijck and B. Van Mele

Abstract  

Modulated temperature differential scanning calorimetry (MTDSC) is used to study simultaneously the evolution of heat flow and heat capacity for the isothermal and non-isothermal cure of an epoxy-anhydride thermosetting system. Modelling of the (heat flow related) chemical kinetics and the (heat capacity related) mobility factor contributes to a quantitative construction of Temperature-Time-Transformation (TTT) and Continuous-Heating-Transformation (CHT) diagrams for the thermosetting system.

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Journal of Thermal Analysis and Calorimetry
Authors: C. A. Gracia-Fernández, P. Davies, S. Gómez-Barreiro, Beceiro J. López, J. Tarrío-Saavedra, and R. Artiaga

.1016/0040-6031(95)02693-2 . 20. Hemelrijck , AV , Mele , BV 1997 Modulated temperature differential scanning calorimetry. Characterization of curing systems by TTT and CHT diagrams . J Therm Anal 49 : 437 – 442 10.1007/BF01987467

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