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, the LESO outperforms NESO in terms of uncertainty estimation. The LESO gives better estimation accuracy of uncertainty as compared to that based on NESO. Table 2. Performance evaluation of ESOs Type of Estimation Error RMSE LESO NESO Tracking

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Abstract  

The calorimetry exchange (CALEX) program is administered by New Brunswick Laboratory (NBL). The main objective of the program is to provide an independent verification of the internal quality control practices in nuclear material safeguards facilities making plutonium accountability measurements by non-destructive calorimetry/gamma spectrometry techniques. Facilities measure the calorimetric power, and plutonium and 241Am isotope abundances of CALEX program standards using routine accountability procedures. The measurement results as well as two other quantities (effective specific power and plutonium mass) calculated from these results are evaluated for accuracy (or bias) and precision. In this paper, a limited number of measurement results of a CALEX program standard (identified as Calex I) are evaluated with specific goals to identify a suitable method for uncertainty estimation and to identify the major contributors to the uncertainties. In order to achieve the goals, the Calex I measurement results were evaluated using two different methods: the first method confined to uncertainty estimation from random variations of the measurement results alone, and the second method providing a more comprehensive evaluation of uncertainties from both the measurements and the characterized values of the measured standard according to the Guide to the Expression of Uncertainty in Measurement (GUM). The results of this study, and a subsequent study extended to a larger number of results in the CALEX program database, are expected to provide relevant input for developing the International Target Values for plutonium measurements by the calorimetry/gamma spectrometry method.

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Abstract  

A program for qualitative and quantitative analysis of spectra obtained by comparative NAA method is described. It includes peak search, calculation of essential peak parameters, isotope identification and estimation of concentrations and/or detection limits of nuclides, corrected for cooling time and decay during measurement. Corrections for blank samples and peak interference are performed as well. Uncertainties estimation of final results are performed according to the error propagation law. The program is aimed to help an experienced user to calculate the results of analysis but the possibility for automatic mode for routine analysis is provided as well.

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Abstract  

Intelligent design of chemical-process equipment requires accurate thermophysical property values for pure components and mixtures including solutions. Databases used by practicing engineers should include the best numbers available and estimated uncertainties of these numbers. Many important property values have not been measured and must be estimated. Care should be exercised in selecting the estimation method. Property values that are a function of temperature, pressure, and/or composition can be correlated using appropriate equations. Such equations and the number of adjustable parameters in these equations should be selected with care. Examples of determining uncertainties, estimation techniques used, and correlating equations are given.

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Vitamin B6 analysis by reverse-phase high performance liquid chromatography and its validation in milk powder prompted this study. The calibration curves for pyridoxal, pyridoxamine and pyridoxine were evaluated and method precision and accuracy assessed. It was found that the working range was adequate for all the analytes. The analytical procedure was verified by testing the enzymatic efficiency, precision and accuracy. In milk powder samples pyridoxine was the only vitamer found in quantities above the considered limit of quantification and the accuracy showed Z-scores lower than 2. Uncertainty estimation based on method validation results was 0.066 mg/100g, for a vitamin B6 content of 0.61 mg/100 g. It was concluded that the method is adequate for vitamin B6 quantification in powder milk.

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Thermal diesel-like analysis

Quality control by thermal and chemometric analysis

Journal of Thermal Analysis and Calorimetry
Authors:
Alexandre G. S. Prado
,
Rômulo D. A. Andrade
,
Jez W. B. Braga
, and
Paulo A. Z. Suarez

, JH , Mark , H . 2006 . Uncertainty estimation and ures of merit for multivariate calibration . Pure Appl Chem . 78 : 633 – 661 10.1351/pac200678030633 . 30. Miller-Ihli , NJ , O

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. Ulrich . “ Uncertainty estimation and multi sensor fusion for kinematic laser tracker measurements ,” Metrologia , vol. 50 , pp. 307 – 317 , 2013 . 10

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-1354(98)00463-1 . Beven , K , Freer , J 2001 Equifinality, data assimilation, and uncertainty estimation in mechanistic modelling of complex environmental systems using the GLUE methodology . Journal of Hydrology 249 1–4 11 – 29 10.1016/S0022

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