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The state of water and several transitions were examined in the systemsn-decanephosphonic acid (DPA)—water and the sodium salts of DPA—water. Temperature — composition phase diagrams are reported. The results show that several liquid crystalline phases plus isotropic liquid, and two solid phases (a waxy solid phase and a crystalline phase) are formed. Several types of water were detected: bulk-like water, interfacial water and hydration water.

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