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Ce2O3-K2O-P2O5 ternary system has been investigated by thermoanalytical methods (DTA, DSC), powder X-ray diffraction, XPS and IR spectroscopy. The existence of three double potassium-cerium(III) phosphates has been confirmed and a new binary phosphate K4Ce2P4O15 has been found. Phase diagram and isothermal section at room temperature of the system Ce2O3-K2O-P2O5 have been presented.

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