Authors:N. Sh. Lebedeva, N. A. Pavlycheva, V. P. Kulinich, G. P. Shaposhnokov, and E. V. Parfenyuk
Summary Processes of thermooxidizing destruction of series of oxygen containing cobalt(II)phthalocyanines were studied by thermogravimetry and IR and electronic absorption spectroscopy. These processes have several stages including dehydration, oxidation, desulphonation (decarboxylation) of peripheral substituents of cobalt(II)phthalocyanines, destruction of phthalocyanine macrocycle and oxidation until the highest oxides. The temperature of beginning of the process of thermal oxidative destruction decreases in the following order: Co(4-PhSO3H)4Pc>Co(4-COO-)4(5-SO-3)4(Ba2+)4Pc>Co(4-Br)4(5-SO3H)4Pc>Co(4-Cl)4(5-SO3H)4Pc>Co(4-COOH)4(5-SO3H)4Pc.
Authors:S. Qiu, H. Chu, J. Zhang, Y. Qi, L. Sun, and F. Xu
The low-temperature molar heat capacities of CoPc and CoTMPP were measured by temperature modulated differential scanning
calorimetry (TMDSC) over the temperature range from 223 to 413 K for the first time. No phase transition or thermal anomaly
was observed in the experimental temperature range for CoPc. However, a structural change was found to be nonreversible for
CoTMPP in the temperature range of 368–403 K, which was further validated by the results of IR and XRD. The molar enthalpy
ΔHm and entropy ΔSm of phase transition of the CoTMPP were determined to be 3.301 kJ mol−1 and 8.596 J K−1 mol−1, respectively. The thermodynamic parameters of CoPc and CoTMPP such as entropy and enthalpy relative to reference temperature
298.15 K were derived based on the above molar heat capacity data. Moreover, the thermal stability of these two compounds
was further investigated through TG measurements. Three steps of mass loss were observed in the TG curve for CoPc and five
steps for CoTMPP.