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Parent and mixed ligand complexes of cobalt(II) and copper(II) ions with N,N'-bis- (4-antipyrylmethyl)piperazine or N,N'-tetra(4-antipyryl-methyl)-1,2-diaminoethane or/and imidazole as ligand and ClO4- or SCN- as counterion were synthesised and their thermal behaviour was investigated.

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