Authors:N. Rajurkar, D. Zinjad, S. Zambare, and A. Shah
The instrumental neutron activation analysis (INAA) of industrially important steel samples, viz. IS-226, IS-2002, IS-2062, SS-304, SS-310, SS-316 and of copper base alloys, viz. high brass, gun metal and copper-silver alloys is carried out with a 2 Ci252Cf neutron source. The copper and vanadium content of all the steel samples and manganese content of former three steel samples are estimated by measuring the gamma activity of66Cu,52V and56Mn radioisotopes, respectively, using a high purity germanium (HPGe) detector coupled to a 4 K multichannel analyzer (MCA). Similarly, the copper content of copper base alloys was also determined.
Thermal behavior of α-(Cu–Al–Ag) alloys, i.e. alloys
with composition less than about 8.5 mass% Al, was studied using differential
scanning calorimetry (DSC), differential thermal analysis (DTA), scanning
electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and X-ray
diffractometry (XRD). The results indicated that the presence of silver introduces
new thermal events ascribed to the formation of a silver-rich phase and, after
addition higher amounts than 8 mass% Ag to the Cu–8 mass% Al alloy it
is possible to observe the formation of the γ1
phase (Al4Cu9), which is only
observed in alloys containing minimum of 9 mass% Al. These results may be
attributed to some Ag characteristics and its interaction with Cu and Al.
Authors:A. Adorno, M. Guerreiro, C. Ribeiro, and C. Guerreiro
The influence of additions of 2, 4, 6, 8, 10 and 12 mass% Ag on the thermal behavior of the Cu–8 mass% Al alloy was studied
using differential scanning calorimetry (DSC), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX)
and X-ray diffractometry (XRD). The results indicate that the presence of silver introduces new thermal events, due to the
formation of a silver-rich phase and, for additions of 10 and 12 mass% Ag, it is possible to verify the formation of the γ1 phase (Cu9Al4) and the metastable transitions which are only observed in alloys with a minimum of 9 mass% Al.