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Journal of Thermal Analysis and Calorimetry
Authors: J. Regis Botelho, A. Duarte Gondim, I. Garcia dos Santos, P. Dunstan, A. Souza, V. Fernandes, and A. Araújo


The standard molar enthalpy of formation of crystalline dialkyldithiocarbamate chelates, [Pd(S2CNR2)2], with R=CH3 and i-C3H7, was determined through reaction-solution calorimetry in 1,2-dichloroethane, at 298 K. Using the standard molar enthalpies of formation of the gaseous chelates, the homolytic (52618 and 66610) and heterolytic (269318 and 295710 kJ mol-1) mean enthalpies of palladium-sulphur bond dissociation were calculated.

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