View More View Less
  • 1 University of Novi Sad, Faculty of Sciences Institute of Chemistry 21000 Novi Sad Trg D. Obradovicá 3 Yugoslavia 21000 Novi Sad Trg D. Obradovicá 3 Yugoslavia
  • | 2 Technical University of Budapest Research Group for Technical Analytical Chemistry of the Hungarian Academy of Sciences at the Institute for General and Analytical Chemistry H-1521 Budapest H-1521 Budapest
  • | 3 Technical University of Budapest Institute for General and Analytical Chemistry H-1521 Budapest Hungary H-1521 Budapest Hungary
  • | 4 Faculty of Metallurgy and Technology Podgorica Yugoslavia Podgorica Yugoslavia
Restricted access

Abstract  

Complexes represented by the general formula [MCl2L2] (M(II)=Zn, Mn, Co) and complexes of [Cu3Cl6L4] and CuSO4L24H2O, CoSO4L23H2O, [ZnSO4L3] where L stands for 3-amino-5-methylpyrazole were prepared. The complexes were characterized by elemental analysis, FT-IR spectroscopy, thermal (TG, DTG, DSC and EGA) methods and molar conductivity measurements. Except for the Zn-complexes, the magnetic susceptibilities were also determined. Thermal decomposition of the sulphato complexes of copper(II) and cobalt(II) and the chloro complexes of cobalt(II) and manganese(II) resulted in well-defined intermediates. On the basis of the IR spectra and elemental analysis data of the intermediates a decomposition scheme is proposed.

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

For subscription options, please visit the website of Springer.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jun 2021 0 0 0
Jul 2021 0 0 0
Aug 2021 0 0 0
Sep 2021 0 0 0
Oct 2021 0 0 0
Nov 2021 1 0 0
Dec 2021 0 0 0