Acta Chromatographica
Volume/Issue:
Volume 27: Issue 1
Development and validation of an ultrasound-assisted surfactant-enhanced emulsification microextraction method for liquid chromatographic determination of carbamate residues in fruit juices
Authors:
J. Vichapong Khon Kaen University Materials Chemistry Research Unit, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science Khon Kaen 40002 Thailand

Search for other papers by J. Vichapong in
Current site
Google Scholar
PubMed Close
and
R. Burakham Khon Kaen University Materials Chemistry Research Unit, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science Khon Kaen 40002 Thailand

Search for other papers by R. Burakham in
Current site
Google Scholar
PubMed Close
Pages:
127–145
Online Publication Date:
23 Dec 2013
Publication Date:
01 Mar 2015
Article Category:
Research Article
DOI:
https://doi.org/10.1556/achrom.27.2015.1.10
Keywords:
ultrasound-assisted surfactant-enhanced emulsification microextraction; HPLC; monolithic column; carbamates; fruit juice
Open access
Get Permissions

A microextraction procedure based on ultrasound-assisted surfactant-enhanced emulsification microextraction (UASEME) was optimized and validated for preconcentration of carbamate pesticides prior to fast determination using high-performance liquid chromatography (HPLC) with monolithic column. The nonionic surfactant (Tween 20) was used as an emulsifier, and chloroform was selected as an extraction solvent. The experimental parameters affecting the extraction efficiency, such as the kind, concentration, and volume of surfactant, the kind of extraction solvent and its volume, salt addition, ultrasonic extraction time, and centrifugation time, were optimized. Under the selected UASEME and HPLC conditions, separation of five carbamate pesticides (carbofuran, carbaryl, isoprocarb, methiocarb, and promecarb) was achieved within 10 min. The linearity of the method was obtained in the wide range of 2–5000 μg L−1, with correlation coefficients of 0.9931–0.9970. The limits of detection were in the range of 0.4–7.0 μg L−1. The relative standard deviations (n = 5) were less than 0.59% and 4.86% for retention time and peak area, respectively. The enrichment factors of the developed UASEME method were in the range of 33–166. The fruit juice samples (at fortified levels of 0.25, 0.50, and 1.00 mg L−1) were successfully analyzed, and the relative recoveries were obtained in the range of 81–115%.

  • N. Chu and S. Fan, Spectrochim. Acta A, 74, 1173–1180 (2009)

    Fan S. , '' (2009 ) 74 Spectrochim. Acta A : 1173 -1180 .

  • A.M. Filho, F.N. dos Santos, and P.A. de P Pereira, Microchem. J., 96, 139–145 (2010)

    de P Pereira P.A. , '' (2010 ) 96 Microchem. J. : 139 -145 .

  • National Bureau of Agricultural Commodity and Food Standards (ACFS) (2008) http://www.acfs.go.th/eng/index.php (accessed April 30, 2013)

  • A. Santalad, S. Srijaranai, R. Burakham, T. Sakai, and R.L. Deming, Microchem. J., 90, 50–55 (2008)

    Deming R.L. , '' (2008 ) 90 Microchem. J. : 50 -55 .

  • L. Alvarez-Rodríguez, L. Monferrer-Pons, J.S. Esteve-Romero, M.C. García-Alvarez-Coque, and G. Ramis-Ramos, The Analyst, 122, 459–463 (1997)

    Ramis-Ramos G. , '' (1997 ) 122 The Analyst : 459 -463 .

  • Y. Ni, P. Qiu, and S. Kokot, Anal. Chim. Acta, 537, 321–330 (2005)

    Kokot S. , '' (2005 ) 537 Anal. Chim. Acta : 321 -330 .

  • M.J. Santos Delgado, S. Rubio Barroso, G. Toledano Fernández-Tostado, and L.M. Polo-Díez, J. Chromatogr., A, 921, 287–296 (2001)

    Polo-Díez L.M. , '' (2001 ) 921 J. Chromatogr., A : 287 -296 .

  • A. Santalad, S. Srijaranai, R. Burakham, J.D. Glennon, and R.L. Deming, Anal. Bioanal. Chem., 394, 1307–1317 (2009)

    Deming R.L. , '' (2009 ) 394 Anal. Bioanal. Chem. : 1307 -1317 .

  • J. Vichapong, R. Burakham, S. Srijaranai, and K. Grudpan, Talanta, 84, 1253–1258 (2011)

    Grudpan K. , '' (2011 ) 84 Talanta : 1253 -1258 .

  • J. Vichapong, R. Burakham, S. Srijaranai, and K. Grudpan, J. Sep. Sci., 34, 1574–1581 (2011)

    Grudpan K. , '' (2011 ) 34 J. Sep. Sci. : 1574 -1581 .

  • A. Santalad, L. Zhou, F. Shang, D. Fitzpatrick, R. Burakham, S. Srijaranai, J.D. Glennon, and J.H.T. Luong, J. Chromatogr., A, 1217, 5288–5297 (2010)

    Luong J.H.T. , '' (2010 ) 1217 J. Chromatogr., A : 5288 -5297 .

  • S. Zhang, C. Li, S. Song, T. Feng, C. Wang, and Z. Wang, Anal. Methods, 2, 54–62 (2010)

    Wang Z. , '' (2010 ) 2 Anal. Methods : 54 -62 .

  • L. He, C. Wang, Y. Sun, X. Luo, J. Zhang, and K. Lu, Int. J. Environ. Anal. Chem., 89, 439–448 (2009)

    Lu K. , '' (2009 ) 89 Int. J. Environ. Anal. Chem. : 439 -448 .

  • Q. Wu, X. Zhou, Y. Li, X. Zang, C. Wang, and Z. Wang, Anal. Bioanal. Chem., 393, 1755–1761 (2009)

    Wang Z. , '' (2009 ) 393 Anal. Bioanal. Chem. : 1755 -1761 .

  • Z.M. Liu, X.H. Zang, W.H. Liu, C. Wang, and Z. Wang, Chin. Chem. Lett., 20, 213–216 (2009)

    Wang Z. , '' (2009 ) 20 Chin. Chem. Lett. : 213 -216 .

  • H.-P. Li, J.-H. Li, G.-C. Li, and J.-F. Jen, Talanta, 63, 547–553 (2004)

    Jen J.-F. , '' (2004 ) 63 Talanta : 547 -553 .

  • F. Koc, Y. Yigit, Y.K. Das, Y. Gurel, and C. Yarali, J. Food Drug Anal., 16, 39–45 (2008)

    Yarali C. , '' (2008 ) 16 J. Food Drug Anal. : 39 -45 .

  • T. Perez-Ruiz, C. Martinez-Lozano, and M.D. Garcia, J. Chromatogr., A, 1164, 174–180 (2007)

    Garcia M.D. , '' (2007 ) 1164 J. Chromatogr., A : 174 -180 .

  • S.S. Caldas, F.P. Costa, and E.G. Primel, Anal. Chim. Acta, 665, 55–62 (2010)

    Primel E.G. , '' (2010 ) 665 Anal. Chim. Acta : 55 -62 .

  • J. Vichapong and R. Burakham, Anal. Methods, 4, 2101–2108 (2012)

    Burakham R. , '' (2012 ) 4 Anal. Methods : 2101 -2108 .

  • S.M. Goulart, R.D. Alves, A.A. Neves, J.H. de Queiroz, T.C. de Assis, and M.E.L.R. de Queiroz, Anal. Chim. Acta, 671, 41–47 (2010)

    de Queiroz M.E.L.R. , '' (2010 ) 671 Anal. Chim. Acta : 41 -47 .

  • Y. Santaladchaiyakit, S. Srijaranai, and R. Burakham, J. Sep. Sci., 35, 2373–2389 (2012)

    Burakham R. , '' (2012 ) 35 J. Sep. Sci. : 2373 -2389 .

  • J. López-Darias, M. Germán-Hernández, V. Pino, and A.M. Afonso, Talanta, 80, 1611–1618 (2010)

    Afonso A.M. , '' (2010 ) 80 Talanta : 1611 -1618 .

  • P. Plaza Bolaños, R. Romero-González, A. Garrido Frenich, and J.L. Martínez Vidal, J. Chromatogr., A, 1208, 16–24 (2008)

    Martínez Vidal J.L. , '' (2008 ) 1208 J. Chromatogr., A : 16 -24 .

  • Q. Zhou, L. Pang, and J. Xiao, Microchim. Acta, 173, 477–483 (2011)

    Xiao J. , '' (2011 ) 173 Microchim. Acta : 477 -483 .

  • L. Fu, X. Liu, J. Hu, X. Zhao, H. Wang, and X. Wang, Anal. Chim. Acta, 632, 289–295 (2009)

    Wang X. , '' (2009 ) 632 Anal. Chim. Acta : 289 -295 .

  • C. Zheng, J. Zhao, P. Bao, J. Gao, and J. He, J. Chromatogr., A, 1218, 3830–3836 (2011)

    He J. , '' (2011 ) 1218 J. Chromatogr., A : 3830 -3836 .

  • J. Regueiro, M. Llompart, C. Garcia-Jares, J.C. Garcia-Monteagudo, and R. Cela, J. Chromatogr., A, 1190, 27–38 (2008)

    Cela R. , '' (2008 ) 1190 J. Chromatogr., A : 27 -38 .

  • Q. Wu, Q. Chang, C. Wu, H. Rao, X. Zeng, C. Wang, and Z. Wang, J. Chromatogr., A, 1217, 1773–1778 (2010)

    Wang Z. , '' (2010 ) 1217 J. Chromatogr., A : 1773 -1778 .

  • J. Cheng, G. Matsadiq, L. Liu, Y. Zhou, and G. Chen, J. Chromatogr., A, 1218, 2476–2482 (2011)

    Chen G. , '' (2011 ) 1218 J. Chromatogr., A : 2476 -2482 .

  • J. Cheng, Y. Xia, Y. Zhou, F. Guo, and G. Chen, Anal. Chim. Acta, 701, 86–91 (2011)

    Chen G. , '' (2011 ) 701 Anal. Chim. Acta : 86 -91 .

  • Y. Yamini and M. Moradi, J. Sep. Sci., 35, 2319–2340 (2012)

    Moradi M. , '' (2012 ) 35 J. Sep. Sci. : 2319 -2340 .

  • A.S. Yazdi and Z. Es'haghi, J. Chromatogr., A, 1094, 1–8 (2005)

    Es'haghi Z. , '' (2005 ) 1094 J. Chromatogr., A : 1 -8 .

  • Document N° SANCO/12495/2011, Method Validation and Quality Control Procedures for Pesticide Residues Analysis in Food and Feed, http://www.crl-pesticides.eu/library/docs/fv/SANCO12495-2011.pdf (accessed June 4, 2013).

  • Collapse
  • Expand
Cover Acta Chromatographica
Acta Chromatographica
Online ISSN:
2083-5736

Senior editors

Editor(s)-in-Chief: Sajewicz, Mieczyslaw, University of Silesia, Katowice, Poland

Editors(s)

  • Danica Agbaba, University of Belgrade, Belgrade, Serbia (1953-2024)
  • Łukasz Komsta, Medical University of Lublin, Lublin, Poland
  • Ivana Stanimirova-Daszykowska, University of Silesia, Katowice, Poland
  • Monika Waksmundzka-Hajnos, Medical University of Lublin, Lublin, Poland

Editorial Board

  • Ravi Bhushan, The Indian Institute of Technology, Roorkee, India
  • Jacek Bojarski, Jagiellonian University, Kraków, Poland
  • Bezhan Chankvetadze, State University of Tbilisi, Tbilisi, Georgia
  • Michał Daszykowski, University of Silesia, Katowice, Poland
  • Tadeusz H. Dzido, Medical University of Lublin, Lublin, Poland
  • Attila Felinger, University of Pécs, Pécs, Hungary
  • Kazimierz Glowniak, Medical University of Lublin, Lublin, Poland
  • Bronisław Glód, Siedlce University of Natural Sciences and Humanities, Siedlce, Poland
  • Anna Gumieniczek, Medical University of Lublin, Lublin, Poland
  • Urszula Hubicka, Jagiellonian University, Kraków, Poland
  • Krzysztof Kaczmarski, Rzeszow University of Technology, Rzeszów, Poland
  • Huba Kalász, Semmelweis University, Budapest, Hungary
  • Katarina Karljiković Rajić, University of Belgrade, Belgrade, Serbia
  • Imre Klebovich, Semmelweis University, Budapest, Hungary
  • Angelika Koch, Private Pharmacy, Hamburg, Germany
  • Piotr Kus, Univerity of Silesia, Katowice, Poland
  • Debby Mangelings, Free University of Brussels, Brussels, Belgium
  • Emil Mincsovics, Corvinus University of Budapest, Budapest, Hungary
  • Ágnes M. Móricz, Centre for Agricultural Research, Budapest, Hungary
  • Gertrud Morlock, Giessen University, Giessen, Germany
  • Anna Petruczynik, Medical University of Lublin, Lublin, Poland
  • Robert Skibiński, Medical University of Lublin, Lublin, Poland
  • Bernd Spangenberg, Offenburg University of Applied Sciences, Germany
  • Tomasz Tuzimski, Medical University of Lublin, Lublin, Poland
  • Adam Voelkel, Poznań University of Technology, Poznań, Poland
  • Beata Walczak, University of Silesia, Katowice, Poland
  • Wiesław Wasiak, Adam Mickiewicz University, Poznań, Poland
  • Igor G. Zenkevich, St. Petersburg State University, St. Petersburg, Russian Federation

 

SAJEWICZ, MIECZYSLAW
E-mail:mieczyslaw.sajewicz@us.edu.pl

Indexing and Abstracting Services:

  • Science Citation Index
  • SCOPUS
  • DOAJ
  • Sci Search
  • Research Alert
  • Chemistry Citation Index and Current Content/Physical
  • Chemical and Earth Sciences
  • GoogleScholar
  • Index Copernicus
  • CABI
  • CABELLS Journalytics

2024  
Web of Science  
Journal Impact Factor 1.7
Rank by Impact Factor Q3 (Chemistry, Analytical)
Journal Citation Indicator 0.44
Rank by Journal Citation Indicator Q3 (Chemistry, Analytical)
Scopus  
CiteScore 4.0
CiteScore rank Q2 (General Chemistry)
SNIP 0.577
Scimago  
SJR index 0.285
SJR Q rank Q3

Acta Chromatographica
Publication Model Online only
Gold Open Access
Submission Fee none
Article Processing Charge

700 EUR/article

For MS submitted before 1 Feb 2025: 400 EUR/article
Regional discounts on country of the funding agency World Bank Lower-middle-income economies: 50%
World Bank Low-income economies: 100%
Further Discounts Editorial Board / Advisory Board members: 50%
Corresponding authors, affiliated to an EISZ member institution subscribing to the journal package of Akadémiai Kiadó: 100%
Subscription Information Gold Open Access
Purchase per Title  

Acta Chromatographica
Language English
Size A4
Year of
Foundation		 1988
Volumes
per Year		 1
Issues
per Year		 4
Founder Institute of Chemistry, University of Silesia
Founder's
Address		 PL-40-007 Katowice, Poland, Bankowa 12
Publisher Akadémiai Kiadó
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 2083-5736 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jan 2025 0 35 8
Feb 2025 0 54 0
Mar 2025 0 65 1
Apr 2025 0 26 7
May 2025 0 19 2
Jun 2025 0 17 2
Jul 2025 0 0 0