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  • 1 Babeș-Bolyai University, 30 Fântânele Street, 400294 Cluj-Napoca, Romania
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Thin-layer chromatography (TLC) is a frequently used technique for the separation of polar and non-polar compounds, with a rich literature in this field. The aim of this paper is to show the TLC adsorbent quality of the Nevşehir volcanic tuff from Turkey that is compared with the Mirșid volcanic tuff from Romania. Our experimental investigations have shown that it is possible to achieve TLC plates coated with Nevşehir volcanic tuff, in natural occurrence, excepting grinding and sieving processes, which can be used for the separation of polar compounds, such as amino acids or food dyes. In the present article, modern techniques for characterizing the volcanic tuff powders, namely, X-ray diffraction, inductively coupled plasma–optical emission spectrometry, scanning electron microscopy, specific surface area and porosity measurements, and infrared spectroscopy, were used in addition to the chromatographic testing. TLC plates coated with Nevşehir tuff were prepared and tested at the separation of some amino acids, obtaining good results. Also, the impregnation of Nevşehir tuff with NaOH and NaCl, respectively, allowed the separation of some hydrophilic dyes. The obtained results have contributed to understand the chromatographic properties of the Nevşehir volcanic tuff. The TLC capability of the Nevşehir tuff can enlarge the pallete of inexpensive adsorbents with possible applications in the field of layer chromatographic separations.

  • [1]

    V. Zubkov , General Petrography, Mir Publishers, Moscow, 1972, pp. 161165.

  • [2]

    C. Sârbu , T. Hodișan, C. Liteanu, C. Măruțoiu, Rev. Chim. (Bucharest) 31 (1980) 288290.

  • [3]

    V. Coman , C. Măruţoiu, J. Planar Chromatogr. 7 (1994) 450452.

  • [4]

    C. Karakurt , I.B. Topçu, 1st International Symposium on Sustainable Development, Sarajevo, June 9–10, 2009, 150156.

  • [5]

    A. Măicăneanu , H. Bedelean, M. Stanca, Natural Zeolites – Characterization and Applications in the Environmental Protection (Zeoliții naturali. Caracterizare și aplicații în protecția mediului), Cluj University Press Publishing House, Cluj-Napoca, 2008, pp. 116122 (Romanian).

    • Search Google Scholar
    • Export Citation
  • [6]

    J.J. Fripiat , G. Poncelet, A.T. Van Assche, J. Mayaudon, Clays Clay Miner. 20 (1972) 331339.

  • [7]

    E. Izci , A. Izci, Turk J. Chem. 31 (2007) 523530.

  • [8]

    C. Măruțoiu , C. Sârbu, C. Liteanu, Romanian Patent 79138, 1982.

  • [9]

    C. Măruțoiu , R. Constantinescu, F. Dogar, V. Coman, I. Sarachie, Acta Chromatogr. 8 (1998) 3947.

  • [10]

    E. Yasar , A. Tolgay, A. Teymen, World Appl. Sci. J. 7 (2009) 271284.

  • [11]

    A. Baba , A. Kaya, N. Turk, J. Applied Sci. 5 (2005) 800805.

  • [12]

    O. Türkdönmez , M. Bozcu, OJG. 2 (2012) 2533.

  • [13]

    A. Yildiz , A. Gürel, Y.G. Dursun, Bull. Min. Res. Exp. 152 (2016) 165180.

  • [14]

    S. Ergül , I. Kadan, Ş. Savaşci, S. Ergül, J. Chromatogr. Sci. 43 (2005) 394400.

  • [15]

    O.F. Măruțoiu , I. Bratu, S. Hodișan, C. Tigae, Croat. Chem. Acta 87 (2014) 16.

  • [16]

    M.-V. Coman , Silicon Compounds Used as Stationary Phases in Liquid Chromatography (Compuşi ai siliciului utilizaţi ca faze staționare în cromatografia de lichide), PhD Thesis, UBB Cluj-Napoca, 1997 (Romanian).

    • Search Google Scholar
    • Export Citation
  • [17]

    V. Pelloni-Tamaș , F. Johan, Thin Layer Chromatography (Cromatografia în strat subțire), Technical Publishing House, Bucharest, 1971, p. 37 (Romanian).

    • Search Google Scholar
    • Export Citation
  • [18]

    V. Coman , Şt. Kreibik, in: E. Tyihák (ed.), Forced-Flow Layer Chromatography, Elsevier, Amsterdam, 2016, Chapter 5, pp. 285345.

  • [19]

    E. Stahl , Thin-Layer Chromatography – A Laboratory Handbook, Springer-Verlag, Berlin, 1969.

  • [20]

    C. Giannini , M. Ladisa, D. Altamura, D. Siliqi, T. Sibillano, L. De Caro, Crystals 6 (2016) 87109.

  • [21]

    I.C. Popescu , Crystallography. Mineralogy. (Cristalografie. Mineralogie.), Didactic and Pedagogical Publishing House, Bucharest, 1968 (Romanian).

    • Search Google Scholar
    • Export Citation
  • [22]

    K.S.W. Sing , D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol, T. Siemieniewska, Pure Appl. Chem. 57 (1985) 603619.

  • [23]

    F. Rouquerol , J. Rouquerol, K.S.W. Sing, P. Llewellyn, G. Maurin, Adsorption by Powders and Porous Solids: Principles, Methodology and Applications, 2nd Edition, Academic Press, Kidlington, Oxford, 2014.

    • Search Google Scholar
    • Export Citation
  • [24]

    V.Y. Davydov , A.V. Kiselev, L.T. Zhuravlev, Trans. Faraday Soc. 60 (1964) 22542264.

  • [25]

    L.T. Zhuravlev , Colloids Surf. A 173 (2000) 138.

  • [26]

    K.K. Unger , in: H.E. Bergna, W.O. Roberts (eds), Colloidal Silica. Fundamentals and Applications, CRC Press Taylor and Francis Group, Boca Raton, FL, 2006, pp. 267275.

    • Search Google Scholar
    • Export Citation
  • [27]

    A. Ahmed , E. Gallei, Appl. Spectrosc. 28 (1974), 430433.

  • [28]

    B. Smith , Infrared Spectral Interpretation: A Systematic Approach, CRC Press, Boca Raton, FL, 1998, p. 171.

  • [29]

    F.A. Miller , C.H. Wilkins, Anal. Chem. 24 (1952) 12531294.

  • [30]

    L.H. Little , Infrared Spectra of Adsorbent Species, Academic Press, London, New York, 1966.

  • [31]

    H.A. Szymanski , IR Theory and Practice of Spectroscopy, Plenum Press, New York, NY, 1964.

  • [32]

    J. Goldstein , D.E. Newbury, D.C. Joy, C.E. Lyman, P. Echlin, E. Lifshin, L. Sawyer, J.R. Michael, Scanning Electron Microscopy and X-ray Microanalysis, 3rd Edn., Springer, Berlin, 2003.

    • Search Google Scholar
    • Export Citation
  • [33]

    http://www.fao.org/ag/agn/jecfa-additives/specs/monograph5/additive-238-m5.pdf; accessed: November 30, 2017.

  • [34]

    V. Coman , Şt. Kreibik, J. Planar Chromatogr. 16 (2003) 338346.

  • [35]

    C. Liteanu , S. Gocan, T. Hodișan, H. Nașcu, Liquid Chromatography (Cromatografia de lichide), Scientific Publishing House, Bucharest, 1974 (Romanian).

    • Search Google Scholar
    • Export Citation
  • [36]

    S. Țilenschi , Colloidal Chemistry (Chimie coloidală), Technical Publishing House, Bucharest, 1964 (Romanian).

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Journal of Planar Chromatography - Modern TLC
Language English
Size A4
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